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JOURNAL OF LUMINESCENCE
Volume 173, Issue -, Pages 30-33Publisher
ELSEVIER
DOI: 10.1016/j.jlumin.2015.12.027
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The temperature dependence of the luminescent lifetime of a single crystal of Cu(I) phenanthroline, [Cu (dmp)(PPh3)(2)]BF4 (dmp=2,9-dimethyl-1,10-phenanthroline and PPh3=triphenylphosphine), was measured using a fluorescence lifetime imaging microscope utilizing time-gated CCD detection. At all temperatures between 100 K and 292 K, the single crystals exhibited biexponential luminescent decay as well as non-linear Arrhenius luminescent decay kinetics. Variable temperature single-crystal XRD measurements revealed that the observed behavior is likely not the result of a crystallographic phase transition. (C) 2015 Elsevier B.V. All rights reserved.
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