Journal
POLYMER
Volume 256, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2022.125257
Keywords
Micro; nano layer films; Low -temperature toughening; Polypropylene; Nanolayer blown molding
Categories
Funding
- National Key Research and Development Program of China [2021YFD1700700]
- State Key Laboratory of Polymer Materials Engineering [sklpme2021-2-01]
- Fundamental Research Funds for the Central Universities [2021SCU12066]
- National Engineering Laboratory for Eco-Friendly Polymeric Mate- rials (Sichuan) [EFP-YD2202]
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This study successfully produced PP-based nanolayer films and confirmed that ultra-thin micro/nano layer structure can significantly enhance the low-temperature mechanical properties of the films.
The poor low-temperature mechanical properties of polypropylene (PP) film strongly restrict its applications in low-temperature service conditions like frozen packaging, or cold countries and regions. Here the PP-based films including 8-, 128-and 512-layer, were successfully produced by the self-developed nanolayered blown film technology. The 128-layer film exhibited exceptionally enhancement in the low-temperature mechanical prop-erties, outperforming the commercialized 2-layer film with increments of 389%, 141%, and 126% in tensile impact strength, elongation at break, and tear strength, respectively. The DSC, WAXD, and SAXS results disclosed that the crystalline structure of PP in different micro/nano layer films was nearly identical. So, the ultrathin micro/nano layer structure should be responsible for the robust low-temperature mechanical properties, which dissipated energy during the mechanical break by promoting the large plastic deformation. Briefly, the PP-based micro/nano layer films fabricated by the self-developed nanolayer blown film technology show robust low -temperature mechanical properties, so this work may attract some attention in the polymer film industry.
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