4.6 Article

Effect of Ultrasonic Pretreatment on Flocculation Filtration of Low-Rank Coal Slurry

Journal

MOLECULES
Volume 27, Issue 19, Pages -

Publisher

MDPI
DOI: 10.3390/molecules27196460

Keywords

ultrasonic pretreatment; low-rank coal; flocculation filtration; L-F NMR; filter cake porosity

Funding

  1. Natural Science Foundation of Jiangsu Province [BK20221546]
  2. National Key R&D Program of China [2020YFC1908803]
  3. National Natural Science Foundation of China [52004283]
  4. Social Development Key R&D Program of Xuzhou [KC21285]

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This paper studied the mechanism of ultrasonic pretreatment to promote flocculation and filtration of low-rank coal (LRC) slurry. The results showed that ultrasonic pretreatment can promote the flocculation and filtration performance of LRC slurry, increase the filtration rate, decrease the cake moisture content, and improve the permeability of the filter cake to water.
The efficient filtration of low-rank coal (LRC) slurry was significantly beneficial to the production process of wet coal beneficiation. However, relatively few studies have been reported on novel pretreatment methods for the efficient filtration of LRC slurry. In this paper, the mechanism of ultrasonic pretreatment to promote flocculation and filtration of slurry was studied. The hydrophobic variation of the slurry surface was measured by contact angle and XPS. The flocculation properties of slurry were characterized using zeta potential and FBRM. The effects of filter cake porosity and ultrasonic pretreatment on slurry filtration resistance were calculated by L-F NMR and Darcy's theory. The results showed that the ultrasonic pretreatment promoted the flocculation and filtration performance of LRC slurry, increased the filtration rate, and decreased the cake moisture content. Meanwhile, the contact angle of LRC increased significantly from 50.1 degrees to 67.8 degrees after ultrasonic pretreatment, and the surface tension of the filtrate decreased from 69.5 to 53.31 mN/m. Ultrasonic pretreatment reduced the absolute value of the zeta potential of coal slurry from 24.8 to 21.0 mV, and the average chord length of flocs increased from 5-10 mu m to 25-30 mu m, thus weakening the electrostatic repulsion between coals to promote floc formation. In addition, the pore tests and filtration theory calculations showed that the ultrasonic pretreatment significantly improved the permeability of the filter cake to water and reduced the resistance to slurry during filtration. In particular, the mesopore porosity increased by 9.18%, and the permeability increased by 2.937 x 10(8) m(2). Therefore, this contributed to the reduction of slurry filtration resistance. This research provides an efficient method for promoting the efficient filtration of slurry.

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