4.7 Review

A review study of rare Earth, Cobalt, Lithium, and Manganese in Coal-based sources and process development for their recovery

Journal

MINERALS ENGINEERING
Volume 189, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.mineng.2022.107897

Keywords

Critical minerals; Coal-based materials; Process development; Rare earth elements; Cobalt; Lithium; Manganese

Funding

  1. Department of Energy Small Business Innovation Research [DE-SC0021742]
  2. agency of the United States Government
  3. U.S. Department of Energy (DOE) [DE-SC0021742] Funding Source: U.S. Department of Energy (DOE)

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The majority of countries rely on foreign sources for critical minerals, but coal and coal-based materials present opportunities as alternative sources. This study focuses on extracting and commercializing rare earth elements, cobalt, lithium, and manganese from coal and coal-related sources. Recovering these critical metals from coal can help address the challenges in the global supply chain for critical minerals.
The world's majority predominantly relies on foreign sources for supplying critical minerals. This renders the countries susceptible to supply chain disruption and urges them to develop alternative sources to compete in technological advancements. Among many proven newly identified sources, coal and coal-based materials present their opportunities. Due to the complex structure of coal, many mineral forms can be found in coal -related sources, including critical element-containing minerals. Among the fifty critical elements and minerals defined by the USGS, the rare earth elements, cobalt, lithium, and manganese, are particularly significant as they have enormous importance in high-technology product development. These critical metals can be found in high concentrations in coal-derived sources, such as coal refuse, coal combustion products, and coal acid mine drainage, and be recovered through various separation techniques. This study aims to advance the understanding of these elements' extraction and commercial potential from coal and coal-related sources and help address the world's challenges in the critical mineral supply chain. The concentrations and occurrences of these four com-modities in coal-related sources were first reviewed. Later, their recovery processes were discussed, and a conceptual process flowsheet was proposed to selectively recover the rare earth elements, lithium, cobalt, and manganese from coal-based sources.

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