4.2 Article

Tracking nitrogen-to-nickel ratio and prevalent paramagnetic species in synthetic diamonds by electron spin resonance at 90 K

Journal

MENDELEEV COMMUNICATIONS
Volume 32, Issue 5, Pages 645-648

Publisher

ELSEVIER
DOI: 10.1016/j.mencom.2022.09.026

Keywords

synthetic diamond; impurities; high pressure and high temperature; electron spin resonance; solid state chemistry; analytical chemistry

Funding

  1. Ioffe Institute [0040-2014-0013]
  2. JSPS KAKENHI [16K05758, 19K05410, 26107532]
  3. Hosei University (Japan)

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Nitrogen and nickel are the main impurities in type Ib synthetic diamonds obtained under high pressure and high temperature conditions. The study found that an aluminum getter can prevent nitrogen from penetrating the diamond lattice.
Nitrogen and nickel are the main impurities in the type Ib synthetic diamonds obtained under high pressure and high temperature conditions using nickel-containing catalysts. Nitrogen enters the synthesized diamond from the air. The nickel/nitrogen ratio for the two types of diamonds, obtained with and without an aluminum getter that prevents the diamond crystal lattice from nitrogen penetration, was studied by electron spin resonance at 90 K.

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