4.6 Article

Cu2O thin films grown by magnetron sputtering as solar cell absorber layers

Journal

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.mssp.2022.106818

Keywords

Cuprous oxide; Thin films; Solar cells; Sputtering; Optical and electrical properties

Funding

  1. Science and Engineering Research Board (SERB) , Department of Science and Technology (DST) , Government of India [CRG/2018/000500]
  2. Department of Science and Technology (DST) , New Delhi, India [SR/FST/ETI-015/2011]

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In this study, Cu2O thin films were deposited by reactive magnetron sputtering at different substrate temperatures, and their structural, optical, and electrical properties were investigated for potential use as solar cell absorber layers. The films exhibited p-type conductivity with an optical band gap ranging from 1.82 to 2.07 eV.
In the present work, Cu2O thin films were deposited by reactive magnetron sputtering at different substrate temperatures ranging from 300 to 673 K. The structural, optical and electrical properties of Cu2O films have been studied for their potential use as solar cell absorber layers. X-ray diffraction and Raman studies confirmed the cubic phase of Cu2O . X-ray photoelectron spectroscopy shows the presence of minority CuO phase at the surface. The surface morphology at different substrate temperatures has been studied using the scanning electron mi-croscopy and atomic force microscopy. The optical property of Cu2O thin films has been evaluated with the help of transmittance spectroscopy, photoluminescence spectroscopy and spectroscopic ellipsometry. The optical band gap obtained from the transmittance spectroscopy is found to be in the range of 1.82-2.07 eV. All the films exhibit p-type conductivity with a typical carrier concentration of ~ 10(14) cm(-3).

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