Journal
MATERIALS LETTERS
Volume 327, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.matlet.2022.133079
Keywords
Solar cells; K-dopedSnO(2); Solar energy materials; Sol-gel preparation
Funding
- National Natural Science Foundation of China [61804062]
- Qing Lan Project of Jiangsu Province, Jiangsu provincial university natural science research major program of China [20KJA510006]
- Jiangsu Province Cultivation base for State Key Laboratory of Photovoltaic Science and Technology [SKLPST202105]
- Jiangsu Province Graduate research and practice innovation program [HGYK202118]
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A potassium-doped SnO2 film was fabricated on fluorine-doped tin oxide (FTO) glass using spin-coating technique. The introduction of potassium improved the electrical properties of the SnO2 film, facilitating electron transfer from TiO2 film to FTO glass. Additionally, the K-doped SnO2 compact layer effectively suppressed recombination effects between FTO glass and the electrolyte, resulting in an enhanced short-circuit current density and higher power conversion efficiency for dye-sensitized solar cells (DSSCs) compared to TiO2 and non-doped SnO2/TiO2 films.
SnO2 film doped with potassium has been fabricated by spin-coating technique on fluorine-doped tin oxide (FTO) glass. The electrical properties of the SnO2 film are improved by introducing potassium, which is in favor of electrons transfer from TiO2 film to FTO glass. Meanwhile, the K-doped SnO2 compact layer is beneficial in suppressing the recombination effect between the FTO glass and the electrolyte. As a result, the short-circuit current density of dye-sensitized solar cells (DSSCs) is enhanced from 15.20 mA cm(-2) to 17.48 mA cm(-2). Then, the highest power conversion efficiency is 7.84 % for the optimized DSSC based on the K-doped SnO2/TiO2 film, which is larger than those of the DSSCs based on TiO2 film (7.02 %) and non-doped SnO2/TiO2 film (7.18 %).
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