Journal
MATERIALS LETTERS
Volume 327, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.matlet.2022.133039
Keywords
Porous materials; Sol -gel preparation; Thermal properties
Funding
- Guangdong Basic and Applied Basic Research Project [2019B1515120013]
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This study successfully achieved ambient drying of polyimide aerogel by adding hydrophobic SiO2 nanoparticles as enhancers and inhibitors. The resulting PI/SiO2 aerogel showed similar thermal insulation and mechanical properties to that prepared by supercritical drying.
Ambient drying of polyimide (PI) aerogel is rarely reported due to the strong cross-linking network leading to large shrinkage. In this work, the hydrophobic SiO2 nanoparticles are used as skeleton enhancers and shrinkage inhibitors to maintain the nano-porous network structure and achieve ambient drying of PI/SiO2 aerogels. The results show that the PI/SiO(2 )aerogel prepared by ambient drying has similar thermal insulation and mechanical properties as the PI aerogel prepared by supercritical drying. The PI/SiO2 aerogel prepared by ambient drying is low-cost and simple to operate, which is expected to realize the industrialization and wide engineering application.
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