4.6 Article

One-pot solvothermal synthesis of S-doped LiMn0.5Fe0.5PO4@N/S-doped C core-shell structured composites for lithium-ion batteries

Journal

MATERIALS LETTERS
Volume 323, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.matlet.2022.132586

Keywords

Carbon materials; Lithium-ion batteries; Nanocomposites; Microstructure; Doping

Funding

  1. Key Research and Development Pro-gram of Shaanxi [2021GXLH-Z-079]
  2. National Natural Science Foundation of China [52101096, 52176162, 22008190]
  3. China Postdoctoral Science Foundation [2019TQ0248, 2019M663735]

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Self-assembled core-shell structured S-doped LiMn0.5Fe0.5PO4@N/S-doped C composites were prepared by solvothermal process, which exhibited high discharge capacity.
A self-assembled core-shell structured S-doped LiMn0.5Fe0.5PO4@N/S-doped C composites were prepared by a convenient one-step solvothermal process. The glucose-derived carbon microspheres are coated with LiMn0.5Fe0.5PO4 particles and form secondary particles of core-shell structure. Thioacetamide (TAA) and cetyl-trimethylammonium bromide (CTAB) regulate the growth of LiMn0.5Fe0.5PO4 particles and provide N and S atoms for doping the composites. Electrochemical tests show that appropriate additions of TAA and CTAB can improve the discharge capacity of LiMn0.5Fe0.5PO4 cathodes. The LMFP@G-0.5TC delivers high specific discharge capacities of 166.83 mAh.g(-1) (0.1 C) and 96.47 mAh.g(-1) (10 C).

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