4.7 Article

Precipitation evolution induced by electron beam irradiation in Mg-RE alloys

Journal

MATERIALS CHARACTERIZATION
Volume 192, Issue -, Pages -

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.matchar.2022.112196

Keywords

Magnesium alloys; Phase transition; Electron beam irradiation; Diffusion; Scanning transmission electron microscopy

Funding

  1. Liaoning Provincial Natural Science Foundation of China [2020 -MS -085]

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This study investigates a phase transition from ss S' to ss 1 in a Mg-Y-Ce alloy caused by electron beam irradiation through atomic scale scanning transmission electron microscopy. It is found that the structural evolution from ss S' to ss 1 precipitates can be completed within two minutes for a nanosized particle, mainly due to the increased heat and vacancy concentration generated by the electron beam irradiation accelerating atomic diffusion, particularly along the c-axis direction.
At present, it is of important significance for the microstructure design of rare earth magnesium (Mg-RE) alloys to comprehend the evolutionary mechanisms of metastable precipitation phases. In this study, a phase transition from ss S' to ss 1 caused by electron beam irradiation is studied particularly in a Mg-Y-Ce alloy by means of atomic scale scanning transmission electron microscopy. Results show that the structural evolution from ss S ' to ss 1 precipitates can be accomplished thoroughly within two minutes for a nanosized particle. It is mainly ascribed to the fact that the increasing heat and vacancy concentration generated by electron beam irradiation can greatly accelerate the atomic diffusion, especially along c-axis direction. It is confirmed that the phase transition from ss S' to ss 1 is segmented into the two stages, including the preceding diffusive and the subsequent displacive phase transitions. The findings will provide some useful clues to control effectively the morphologies of precipitates and the precipitation behaviors of Mg-RE alloys.

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