Journal
MACROMOLECULES
Volume -, Issue -, Pages -Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.2c01110
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Funding
- National Science Foundation, Division of Materials Research, Polymers Program [DMR-2103196]
- Ministry of Science and Higher Education of the Russian Federation [075-01056-22-00]
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A new theoretical approach was developed to determine the dipole characteristics of PVDF using broadband dielectric spectroscopy, revealing an increase in active dipole concentration and mobility as temperature increased. This led to higher permittivity and piezoelectric performance in both unpoled and poled PVDF.
In addition to the pronounced ferroelectric property from polar crystalline phases, poly(vinylidene fluoride) (PVDF) and its random copolymers also exhibit high dielectric permittivities as a result of highly mobile dipoles in the amorphous phase. In this study, we developed a new theoretical approach to determine the dipole concentration, dipole moment, dipole-dipole interaction, and rotational dipole mobility for PVDF by means of broadband dielectric spectroscopy. From the permittivity of molten PVDF, the Kirkwood-Fro''hlich g-factor and its temperature dependence were determined and used as global parameters for the simulation of unpoled and highly poled biaxially oriented PVDF (BOPVDF). It was found that the concentration of active dipoles substantially increased as the temperature was increased from -30 to 40 degrees C, indicative of the devitrification of the rigid amorphous fraction (RAF). Both the calculated dipole moment and the g-factor of poled BOPVDF were higher than those of unpoled BOPVDF, resulting in a higher permittivity and piezoelectric performance. In addition, the dipole-dipole interaction was found to increase substantially upon increasing the temperature from -30 to 40 degrees C, leading to an increase of over 4 orders of magnitude in the rotational dipole mobility. This was direct evidence for the devitrification of the RAF in both unpoled and poled BOPVDF.
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