Journal
MACROMOLECULES
Volume 55, Issue 19, Pages 8940-8949Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.2c01306
Keywords
-
Categories
Funding
- Center for Emergent Functional Matter Science of National Yang Ming Chiao Tung University from the Featured Areas Research Center Program
- Ministry of Science and Technology of the Republic of China
Ask authors/readers for more resources
In this study, versatile and on-demand photocontrollable ionic conductive nanocomposite hydrogels were successfully synthesized via host-guest chemistry. The hydrogels showed higher conductivity under visible light irradiation and lower conductivity under UV irradiation, which could be further manipulated by adjusting the surface-area-to-volume ratio of the nanopores and the alkyl chain length of the anions.
Exploring stimuli-responsive ionic-conductive materials is a challenging task and has gained considerable attention owing to their noninvasive manipulation and applications. Here, we demonstrate versatile and on-demand photocontrollable ionic conductive nanocomposite hydrogels via host-guest chemistry. Supramolecular hydrogels containing fi-cyclodextrin (fi-CD) and ionic liquid monomers are synthesized in the nanopores of anodic aluminum oxide (AAO) templates, on which light-responsive azobenzene polymers are tethered. Under visible light irradiation, the fi-CD molecules preferentially form inclusion complexes with the trans-Azo moieties, resulting in higher concentrations of the mobile anions and lower resistances of the hydrogels; under UV irradiation, rather than the cis-Azo moieties, the fi-CD molecules favor assembly with the anions, which leads to lower concentrations of the mobile anions and higher resistances of the hydrogels. By tuning the surface-area-to-volume ratio of the AAO nanopores and the alkyl chain length of the anions, the response amplitudes can be further manipulated.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available