Journal
LASER & PHOTONICS REVIEWS
Volume 17, Issue 1, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/lpor.202200475
Keywords
halide doping; light soaking; perovskite solar cells; thermal evaporation; undoped spiro-OMeTAD
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This study demonstrates the profound impact of doping status of organic hole transport materials (HTMs) on the light soaking effect (LSE) in perovskite solar cells. Undoped HTMs show a tenfold efficiency enhancement under LSE, attributed to increased film conductivity and changes at the interface. Chemical and structural analysis also reveal that halide ions migration and subsequent photodoping of organic HTMs significantly improve film conductivity and hole mobility, leading to enhanced photostability of the devices.
Identification and investigation of light soaking effect (LSE) as well as the associated physical mechanisms are crucial for achieving reliable power output and high stability of solar cells. Here, a profound LSE dependence on doping status of organic hole transport materials (HTMs) in perovskite solar cells is demonstrated. A tenfold efficiency enhancement is realized in the devices based on evaporated undoped HTMs caused by LSE. This light-soaking behavior is attributed to the increased film conductivity, enhanced built-in potential at perovskite/HTM interface, reduced interfacial charge accumulation, and suppressed nonradiative recombination in devices. Besides, chemical and structural analysis reveal that halide ions migration and subsequent photodoping of organic HTMs enables significant improvement of the film conductivity and hole mobility. Moreover, the HTM mobilities are proven to determine the LSE strength and kinetics, causing significant variation in photostability of devices.
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