4.2 Article

Adsorption of brilliant green dye by used-tea-powder: equilibrium, kinetics and thermodynamics studies

Journal

AQUA-WATER INFRASTRUCTURE ECOSYSTEMS AND SOCIETY
Volume 71, Issue 10, Pages 1148-1158

Publisher

IWA PUBLISHING
DOI: 10.2166/aqua.2022.076

Keywords

adsorption; adsorption isotherms; adsorption kinetics; Brilliant Green; green adsorbent; used-tea-powder

Funding

  1. DST, New Delhi
  2. UGC

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The present research explores the use of used-tea-powder (UTP) as a potential adsorbent for the removal of Brilliant Green (BG) dye from aqueous solution. The study analyzes the pore morphology, surface properties, crystalline nature, and thermal stability of UTP, and determines the optimized working conditions for efficient dye removal.
The present research is based on the removal of Brilliant Green (BG) dye from its aqueous solution. Used-tea-powder (UTP) was used as a potential adsorbent to remove BG from aqueous solution. Pore morphology, surface properties, crystalline nature and thermal stability of UTP were assessed by using SEM, FTIR, XRD and TGA analysis. The optimized working conditions were found to be pH 6, UTP dose 100 mg, adsorption time 60 min and BG concentration 100 mg L-1. The q(max) obtained from the Langmuir model was 101.01 mg g(-1) showing the utility of UTP in dye removal. The breakthrough volume and efficiency of the column were evaluated through column adsorption studies in fixed-bed mode. It was found that the pseudo-second-order kinetics model was followed as evaluated by the correlation studies. The calculated thermodynamic parameters showed that the adsorption process was feasible, exothermic and spontaneous.

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