4.2 Article

Preparation of triazine-based functionalized HY zeolite and its application in the green synthesis of tetrahydrobenzo[b]pyran and 1, 4-dihydropyrano [2, 3-c] pyrazole derivatives as a novel mesoporous recyclable nanocatalyst

Journal

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
Volume 19, Issue 12, Pages 4721-4734

Publisher

SPRINGER
DOI: 10.1007/s13738-022-02635-3

Keywords

Nanoparticles; Zeolite; 1, 4-dihydropyrano [2, 3-c]pyrazole; Tetrahydrobenzo[b]pyran; Green chemistry

Funding

  1. Arak University

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The triazine-based functionalized HY zeolite nanoparticles have been successfully used to synthesize pharmaceutically valuable compounds as a heterogeneous catalyst, with mild and green reaction conditions, high yields, and easy operation. The catalyst can be reused at least five times without significant loss of activity.
The triazine-based functionalized HY zeolite nanoparticles have been employed for synthesis of the pharmaceutically valuable 1, 4-dihydropyrano [2, 3-c] pyrazole and tetrahydrobenzo[b]pyran derivatives as a novel, versatile and effectual heterogeneous catalyst and characterized by FT-IR, XRD, BET, FE-SEM, TGA, EDX and MAP. The reactions were carried out under mild and green condition and short reaction times with high yield and easy workup process. The heterogeneous nanocatalyst can be simply recovered and reused for at least five times without considerable loss of activity.

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