4.8 Article

Novel ternary CuO-ZnO-MoS2 composite material for electrochemical CO2 reduction to alcohols

Related references

Note: Only part of the references are listed.
Article Green & Sustainable Science & Technology

Potential application of MoS2 nanoflowers as photocatalysts in cement: Strength, hydration, and dye degradation properties

Run-Sheng Lin et al.

Summary: A new method using MoS2 nanoflowers to prepare cement paste for degradable dyes is proposed. MoS2 nanoflowers can promote early cement hydration, slightly affect the amounts of hydration products, and enhance the degradation effect of rhodamine 6G in cement paste.

JOURNAL OF CLEANER PRODUCTION (2022)

Article Green & Sustainable Science & Technology

Environmental and economic assessment of mariculture systems using a high share of renewable energy sources

Marija Korican et al.

Summary: The increased demand for fish products has led to investments and modernization in aquaculture, but it has also resulted in higher energy needs and greater environmental impact. This study examines the use of renewable energy sources in mariculture systems and evaluates their environmental and economic performance. The results show a reduction in emissions and an increase in profitability when renewable energy sources are utilized.

JOURNAL OF CLEANER PRODUCTION (2022)

Review Green & Sustainable Science & Technology

A critical review on the development of metal-organic frameworks for boosting photocatalysis in the fields of energy and environment

S. Swetha et al.

Summary: Metal-organic frameworks (MOFs) are a unique class of materials with excellent photo catalytic activity, high surface area, and diverse structure, making them ideal candidates for versatile photocatalysts. This review summarizes the range, strategies, synthesis methods, and applications of MOF-based photocatalysts.

JOURNAL OF CLEANER PRODUCTION (2022)

Article Chemistry, Physical

ZnSn nanocatalyst: Ultra-high formate selectivity from CO2 electrochemical reduction and the structure evolution effect

Wenjuan Li et al.

Summary: Introducing tin (Sn) into Zn-based catalyst can significantly increase the formate yield and achieve a high Faradaic efficiency of 94%; a synergistic effect between Zn and Sn favors the production of formate with high selectivity; during the reaction process, the morphology of the ZnSn catalyst evolves from nanoparticles to nanosheets and collapsed structures.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Article Chemistry, Multidisciplinary

Stabilizing Cu2+ Ions by Solid Solutions to Promote CO2 Electroreduction to Methane

Xianlong Zhou et al.

Summary: This study proposes a solid solution strategy to stabilize Cu2+ ions by incorporating them into a CeO2 matrix, which improves the performance of Cu-based catalysts in CO2 reduction reaction and enhances the efficiency of CH4 production.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Article Chemistry, Multidisciplinary

Producing formic acid at low pH values by electrochemical CO2 reduction

Marvin Osskopp et al.

Summary: The electrochemical reduction of CO2 has the potential to become a key technology in the transformation to a sustainable circular carbon economy. However, current challenges in the process, such as the formation of formates instead of formic acid and the difficulty in operating at low pH values, make it unprofitable and costly for downstream processing. The carbonate problem, which reduces the carbon selectivity to faradaic products, is the main challenge. This study evaluates different cell configurations and demonstrates that an electrolyzer equipped with a single-layer gas diffusion electrode, a liquid electrolyte, and a zero-gap anode can achieve and sustain low pH values, paving the way for an industrial production of formic acid.

JOURNAL OF CO2 UTILIZATION (2022)

Article Environmental Sciences

Highly selective electrocatalytic reduction of CO2 to HCOOH over an in situ derived hydrocerussite thin film on a Pb substrate

Da Wang et al.

Summary: A metal oxide electrode has been developed for electrochemical CO2 reduction reaction, exhibiting superior activity and product selectivity. By synthesizing a hydrocerussite thin film on a Pb substrate, the electrode shows high selectivity and activity towards formic acid production.

CHEMOSPHERE (2022)

Article Chemistry, Physical

Sulfurization-derived Cu0-Cu+ sites for electrochemical CO2 reduction to ethanol

Tong Dou et al.

Summary: The research successfully fabricated Cu2S nanorods/copper mesh catalyst, which shows high efficiency in electroreduction of CO2 to ethanol. The high performance is attributed to the high density of Cu-0 and Cu (+) pairs derived from the catalyst, as well as the appropriate Cu-0/Cu (+) ratio.

JOURNAL OF POWER SOURCES (2022)

Article Chemistry, Physical

A facile aqueous-phase synthesis method for small PdCu alloy nanocatalysts to enhance electrochemical CO2 reduction reactivity

Bohyeon Cho et al.

Summary: The study demonstrates that small-sized PdCu alloy nanoparticles synthesized through co-reduction show high activity and selectivity in CO2 reduction reaction, making them suitable for CO2 conversion under high current densities.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Review Chemistry, Physical

Electrochemical CO2 conversion towards syngas: Recent catalysts and improving strategies for ratio-tunable syngas

Yani Hua et al.

Summary: This review examines the catalytic mechanisms of electrochemical CO2-to-syngas conversion and introduces various catalysts for this process. It comprehensively summarizes effective strategies to enhance the catalytic efficiency, as well as discusses the feasibility and future development guidelines for large-scale electrochemical CO2 reduction. This review serves as a guide for the development and application of efficient electrocatalysts for CO2-to-syngas conversion.

JOURNAL OF POWER SOURCES (2022)

Article Chemistry, Physical

Optimizing the CO2 reduction to produce CH3OH using flexible NiMoO4 coatings as a photocatalyst

Manuel Alejandro Avila-Lopez et al.

Summary: This work investigates the CO2 photoreduction for renewable methanol production using NiMoO4 as a visible light-absorbing and electrically conductive photocatalyst. The photocatalyst is deposited on glass fibers through a one-step microwave-hydrothermal method, resulting in a homogeneous coating that facilitates higher surface exposure and easier application in photocatalytic reactors. The operational parameters for CO2 photoreduction are modeled and optimized, with temperature, light filter, and NaHCO3 concentration selected as factors for maximizing CH3OH production. The optimized conditions are determined as 50℃, 1 M NaHCO3, and a yellow light filter, resulting in a CH3OH production of 3365 μmol/(g-h) with an apparent quantum yield of 17.9%. These results are attributed to the synergistic effect of improved CO2 solubility, easier product desorption, and enhanced light absorption on the NiMoO4 coating. The stability of the coating is also demonstrated after consecutive evaluations.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Chemistry, Physical

Effect of Ag cocatalyst on highly selective photocatalytic CO2 reduction to HCOOH over CuO/Ag/UiO-66 Z-scheme heterojunction

Minghui Zhang et al.

Summary: CuO/Ag/UiO-66 catalysts exhibit high selectivity towards HCOOH in photocatalytic CO2 reduction. The formation of a Z-scheme heterojunction between CuO and UiO-66, with Ag as a bridge, promotes charge transfer and separation, leading to the high selectivity. Experimental and theoretical results confirm that CuO is responsible for the activation of CO2, while Ag possesses strong adsorption capacity for *H protons, facilitating the generation of HCOOH.

JOURNAL OF CATALYSIS (2022)

Article Chemistry, Analytical

Cu2O/CuO Electrocatalyst for Electrochemical Reduction of Carbon Dioxide to Methanol

Animesh Roy et al.

Summary: In this study, Cu2O/CuO thin film was successfully fabricated on conductive nickel foam using electrodeposition for electrochemical reduction of CO2 to methanol. The prepared catalyst exhibited good electrocatalytic activity in a CO2 saturated solution and can serve as an efficient electrode for methanol production.

ELECTROANALYSIS (2021)

Article Electrochemistry

Electrochemical reduction of CO2 using oxide based Cu and Zn bimetallic catalyst

Saudagar Dongare et al.

Summary: Cu-based CuO-ZnOx catalysts prepared by co-precipitation method show high selectivity for ethanol production in ERCO2, with CuO-ZnO10 exhibiting the best performance.

ELECTROCHIMICA ACTA (2021)

Article Electrochemistry

Local pH induced electrochemical CO2 reduction on nanostructured Ag for adjustable syngas composition

Jungae Lim et al.

Summary: By controlling the thickness of silver nanostructure, the H2/CO syngas ratio produced by CO2 reduction can be adjusted, promoting CO production and improving syngas composition.

ELECTROCHIMICA ACTA (2021)

Review Green & Sustainable Science & Technology

Photocatalytic and electrocatalytic reduction of CO2 and N2 by Ti3C2 MXene supported composites for a cleaner environment: A review

Adem Sreedhar et al.

Summary: Improving the morphology of Ti3C2 MXene can enhance its efficiency in photocatalytic CO2 reduction, potentially achieving the generation of useful energy-rich hydrocarbon fuels and reducing global warming simultaneously; Ti3C2 MXene supported composites have attracted significant interest in CO2 and N2 reduction, contributing to the development of a sustainable clean society.

JOURNAL OF CLEANER PRODUCTION (2021)

Article Green & Sustainable Science & Technology

MoS2/WO3 heterojunction with the intensified photocatalytic performance for decomposition of organic pollutants under the broad array of solar light

Shelly Singla et al.

Summary: The study synthesized binary composites of MoS2/WO3 with strong photocatalytic performance for efficient degradation of organic pollutants. Surface analysis results confirmed its effectiveness in breaking down pollutants.

JOURNAL OF CLEANER PRODUCTION (2021)

Article Chemistry, Physical

Highly selective and active Cu-In2O3/C nanocomposite for electrocatalytic reduction of CO2 to CO

Yanzhu Ye et al.

Summary: The CuIn2O3/C nanocomposite prepared by solid-phase reduction method exhibits enhanced electrocatalytic activity for the selective reduction of CO2 to CO, showing higher Faraday efficiency and larger current densities under low overpotential. The material also maintains good stability in the electrocatalytic reduction of CO2, demonstrating a novel strategy for converting CO2 into desired products with high energy efficiency and large current density.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Article Chemistry, Multidisciplinary

Nitrogen-doped graphene supported copper nanoparticles for electrochemical reduction of CO2

Saudagar Dongare et al.

Summary: Increasing atmospheric CO2 has negative effects on global climate, prompting interest in utilizing CO2 for value-added products. A nanostructured electrocatalyst of Cu NPs supported on NGN was optimized for high ECR activity. The study showed that Cu-20/NGN exhibited the highest catalytic activity among all tested electrocatalysts, with improved electrode properties and performance validated through potential-controlled electrocatalysis.

JOURNAL OF CO2 UTILIZATION (2021)

Article Chemistry, Physical

CuO and ZnO co-anchored on g-C3N4 nanosheets as an affordable double Z-scheme nanocomposite for photocatalytic decontamination of amoxicillin

Mohsen Moradi et al.

Summary: In this study, CZ@T-GCN nanocomposite was successfully prepared with high photocatalytic activity for efficient degradation of AMOX. The research confirmed that under specific operating parameters, the material can rapidly remove AMOX and has potential for industrial applications.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Multidisciplinary

Highly dispersive trace silver decorated Cu/Cu2O composites boosting electrochemical CO2 reduction to ethanol

Wanyu Su et al.

Summary: The study presents a highly efficient Cu/Cu2O-Ag catalyst for promoting the efficiency and selectivity of CO2 electroreduction to produce ethanol. Trace Ag modification can enhance the C2+ selectivity of the catalyst, while improving the yield and stability of ethanol.

JOURNAL OF CO2 UTILIZATION (2021)

Review Chemistry, Multidisciplinary

Electrochemical CO2 Reduction on Cu: Synthesis-Controlled Structure Preference and Selectivity

Weiwei Quan et al.

Summary: This study focuses on the synthesis-controlled structure preferences and the modulation of intermediates' interactions for the design of Cu catalysts for selective ECO2RR. Various advanced structural engineering approaches, including alloy/compound formation, doping/defect introduction, and specific crystal facets/amorphization, are discussed in relation to diverse synthesis controls for achieving highly selective ECO2RR. Challenges and opportunities in Cu catalyst fabrication for ECO2RR are also addressed.

ADVANCED SCIENCE (2021)

Article Chemistry, Physical

In-Sn alloy core-shell nanoparticles: In-doped SnOx shell enables high stability and activity towards selective formate production from electrochemical reduction of CO2

Jigang Wang et al.

Summary: This study demonstrates the synthesis of stable Sn-In alloy nanoparticles for efficient formate production in electrochemical CO2 reduction. Operando X-ray absorption and Raman spectroscopy confirm the stability of the In-doped tin oxide shell under CO2R conditions.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Environmental Sciences

HKUST-1-derived highly ordered Cu nanosheets with enriched edge sites, stepped (211) surfaces and (200) facets for effective electrochemical CO2 reduction

Da Wang et al.

Summary: A novel Cu nanosheet electrode was successfully synthesized from a metal-organic framework, showing higher efficiency in electrochemical CO2 reduction compared to pristine Cu foil. The electrode exhibited increased CO2 adsorption and a larger electrochemical active surface area, contributing to enhanced CO2R activity and product selectivity.

CHEMOSPHERE (2021)

Article Electrochemistry

Copper-iron dimer for selective C-C coupling in electrochemical CO2 reduction

Heping Xie et al.

Summary: The study systematically investigated the performance of heteronuclear CuFe dimers anchored on nitrogenated carbon monolayers as CO2 reduction electrocatalysts using comprehensive density functional theory computations. The results showed that the strong interaction between the CuFe dimer and nitrogenated carbon matrix improved the CO2 reduction activity and selectivity.

ELECTROCHIMICA ACTA (2021)

Article Chemistry, Physical

Recent advances in heterogeneous catalysts for the effective electroreduction of carbon dioxide to carbon monoxide

Enis Oguzhan Eren et al.

Summary: This review provides an overview of recent advances in developing highly efficient heterogeneous catalysts for the selective electroreduction of CO2 to CO, considering mechanistic investigations and basic catalytic requirements. It compares the efficiency of different combinations of transition metals with various supporting materials, and addresses the current challenges in designing future research in this field.

JOURNAL OF POWER SOURCES (2021)

Article Chemistry, Multidisciplinary

Rapid synthesis of amorphous bimetallic copper-bismuth electrocatalysts for efficient electrochemical CO2 reduction to formate in a wide potential window

Yusong Xiong et al.

Summary: A novel amorphous bimetallic copper-bismuth (Cu-Bi) electrocatalyst has been developed for efficient electrochemical reduction of CO2 to formate, showing high selectivity and stability. Its superior performance is mainly attributed to the numerous reaction sites from the irregular atomic structures.

JOURNAL OF CO2 UTILIZATION (2021)

Review Chemistry, Multidisciplinary

CO2 valorisation towards alcohols by Cu-based electrocatalysts: challenges and perspectives

Hilmar Guzman et al.

Summary: This review discusses recent advances in electrochemical transformation of CO2 to alcohols, with a focus on copper-based electrocatalysts. Various factors affecting reaction activity and selectivities are considered. The review provides insights into the challenges and outlook for practical applications of this technology.

GREEN CHEMISTRY (2021)

Article Green & Sustainable Science & Technology

Energy vulnerability around the world: The global energy vulnerability index (GEVI)

Andrea Gatto et al.

JOURNAL OF CLEANER PRODUCTION (2020)

Article Chemistry, Physical

Ni and nitrogen-codoped ultrathin carbon nanosheets with strong bonding sites for efficient CO2 electrochemical reduction

Zhongjun Ma et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2020)

Article Green & Sustainable Science & Technology

Graphitic carbon nitride bedecked with CuO/ZnO hetero-interface microflower towards high photocatalytic performance

Sethuraman Sivasakthi et al.

RENEWABLE ENERGY (2020)

Review Chemistry, Inorganic & Nuclear

A comprehensive review on synthesis and applications of molybdenum disulfide (MoS2 ) material: Past and recent developments

Deepika Gupta et al.

INORGANIC CHEMISTRY COMMUNICATIONS (2020)

Review Chemistry, Physical

An overview of Cu-based heterogeneous electrocatalysts for CO2 reduction

Jian Zhao et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Review Chemistry, Physical

Electrochemical CO2 reduction: from nanoclusters to single atom catalysts

Fang Lu et al.

SUSTAINABLE ENERGY & FUELS (2020)

Article Multidisciplinary Sciences

Selective electroreduction of carbon dioxide to methanol on copper selenide nanocatalysts

Dexin Yang et al.

NATURE COMMUNICATIONS (2019)

Review Chemistry, Multidisciplinary

Progress and Perspectives of Electrochemical CO2 Reduction on Copper in Aqueous Electrolyte

Stephanie Nitopi et al.

CHEMICAL REVIEWS (2019)

Article Chemistry, Physical

Electrochemical CO2 reduction on copper nanoparticles-dispersed carbon aerogels

Xinxin Xiao et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2019)

Article Chemistry, Multidisciplinary

Structural Sensitivities in Bimetallic Catalysts for Electrochemical CO2 Reduction Revealed by Ag-Cu Nanodimers

Jianfeng Huang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Engineering, Environmental

Electrochemical reduction of CO2 to ethanol using copper nanofoam electrode and 1-butyl-3-methyl-imidazolium bromide as the homogeneous co-catalyst

Reyhaneh Fazel Zarandi et al.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2019)

Article Engineering, Environmental

Electrochemical reduction of CO2 on Ag/MnO2 binary catalyst

Jieun Son et al.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2019)

Article Nanoscience & Nanotechnology

Investigating the Role of Copper Oxide in Electrochemical CO2 Reduction in Real Time

Lily Mandal et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Chemistry, Physical

Metallic nanocatalysts for electrochemical CO2 reduction in aqueous solutions

Yuanxing Wang et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2018)

Review Chemistry, Multidisciplinary

Cu-based nanocatalysts for electrochemical reduction of CO2

Huan Xie et al.

NANO TODAY (2018)

Article Spectroscopy

Dye sensitized solar cells using catalytically active CuO-ZnO nanocomposite synthesized by single step method

Nelsa Abraham et al.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2018)

Article Multidisciplinary Sciences

Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction

Zhe Weng et al.

NATURE COMMUNICATIONS (2018)

Article Chemistry, Physical

Pd-Containing Nanostructures for Electrochemical CO2 Reduction Reaction

Dunfeng Gao et al.

ACS CATALYSIS (2018)

Article Chemistry, Multidisciplinary

Tuning Sn-Catalysis for Electrochemical Reduction of CO2 to CO via the Core/Shell Cu/SnO2 Structure

Qing Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Physical

Enhanced field emission properties of molybdenum disulphide few layer nanosheets synthesized by hydrothermal method

Chandrasekar Perumal Veeramalai et al.

APPLIED SURFACE SCIENCE (2016)

Article Engineering, Chemical

Electrochemical reduction of CO2 to methanol over MWCNTs impregnated with Cu2O

M. Irfan Malik et al.

CHEMICAL ENGINEERING SCIENCE (2016)

Article Chemistry, Multidisciplinary

Ultrathin MoS2 Nanosheets Supported on N-doped Carbon Nanoboxes with Enhanced Lithium Storage and Electrocatalytic Properties

Xin-Yao Yu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Physical

Production of methanol from CO2 electroreduction at Cu2O and Cu2O/ZnO-based electrodes in aqueous solution

Jonathan Albo et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2015)

Article Chemistry, Physical

Nanostructured Metallic Electrocatalysts for Carbon Dioxide Reduction

Qi Lu et al.

CHEMCATCHEM (2015)

Article Multidisciplinary Sciences

Robust carbon dioxide reduction on molybdenum disulphide edges

Mohammad Asadi et al.

NATURE COMMUNICATIONS (2014)

Article Chemistry, Physical

Electrochemical Reduction of CO2 at Copper Nanofoams

Sujat Sen et al.

ACS CATALYSIS (2014)

Review Chemistry, Multidisciplinary

Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene

Sheneve Z. Butler et al.

ACS NANO (2013)

Article Electrochemistry

Electrochemical Reduction of CO2 at Cu Nanocluster/(10(1)over-bar0) ZnO Electrodes

Evan Andrews et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2013)

Article Chemistry, Physical

CuO/ZnO Heterostructured Nanorods: Photochemical Synthesis and the Mechanism of H2S Gas Sensing

Jaehyun Kim et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2012)

Article Chemistry, Multidisciplinary

Aqueous CO2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles

Yihong Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Physical

Recent progress in the electrochemical conversion and utilization of CO2

Neil S. Spinner et al.

CATALYSIS SCIENCE & TECHNOLOGY (2012)

Article Chemistry, Multidisciplinary

Recent advances in catalysts for direct methanol fuel cells

Xiao Zhao et al.

ENERGY & ENVIRONMENTAL SCIENCE (2011)

Article Electrochemistry

Electrochemical Reduction of CO2 to CH3OH at Copper Oxide Surfaces

M. Le et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2011)