4.8 Article

Assessment of the first commercial Prussian blue based sodium-ion battery

Journal

JOURNAL OF POWER SOURCES
Volume 548, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.jpowsour.2022.232036

Keywords

Sodium-ion battery; Prussian blue; Assessments; Performance; Safety; Sustainability

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Novel sodium-ion battery technologies are considered as potential alternatives to lithium-ion batteries for large-scale stationary storage applications. Prussian blue analogues (PBA) have advantages of excellent electrochemical stability, low cost, and high-rate capability. This study evaluates the competitiveness and maturity of a commercial Prussian blue-based sodium-ion battery module and finds that it offers performance characteristics between lithium-ion batteries and supercapacitors. Additionally, the technology exhibits excellent safety and sustainability features.
Novel sodium-ion battery technologies have emerged in recent years and are considered as potential alternatives to lithium-ion batteries for large-scale stationary storage applications. Among different sodium-ion cell chem-istries, Prussian blue analogues (PBA) have advantages of excellent electrochemical stability, low cost, and high -rate capability, thanks to their open-framework lattice suitable for sodium-ion intercalation. The present study assesses the first commercial Prussian blue-based sodium-ion pluggable battery module developed and refined in a joint design effort between Natron Energy and ABB, offering insights into the competitiveness and maturity of sodium-ion technologies. Both single cells and battery modules (32 cells in series) are evaluated and compared with other commercial batteries. Natron's sodium-ion battery cells possess performance characteristics between lithium-ion batteries and supercapacitors in terms of power capability, energy density, and cycle life. In addition, the Natron sodium-ion battery technology shows excellent safety and sustainability features that are not dependent on rare earth elements, critical mining processes, or questionable supply chain implications.

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