4.5 Article

Kinetic models of quantum size effect-directed nanocluster self-assembly in atomic corrals

Journal

JOURNAL OF PHYSICS-CONDENSED MATTER
Volume 34, Issue 48, Pages -

Publisher

IOP Publishing Ltd
DOI: 10.1088/1361-648X/ac9a1d

Keywords

quantum size effect; atomic corrals; nanocluster self-assembly; kinetic model

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This article discusses two simple kinetic models of quantum size effect-directed nanocluster self-assembly in circular atomic corrals. The models correspond to an adsorption and an adsorption-diffusion regimes, which are typical at low and high temperatures respectively. It is found that small variations in the electronic local density of states are the main factor that hinders self-assembly in the latter regime.
Two simple kinetic models of quantum size effect-directed nanocluster self-assembly in circular atomic corrals are discussed. The models correspond to an adsorption (either a physisorption or a chemisorption) and an adsorption-diffusion regimes that are typical at low and high temperatures, respectively. Small magnitudes of a variation of the electronic local density of states is shown to be the prime factor that impedes self-assembly in the latter regime.

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