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JOURNAL OF ORGANIC CHEMISTRY
Volume -, Issue -, Pages -Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c01861
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We present a photocatalyst-free, diastereoselective decarboxylative alkylation method for (hetero)aryl sulfinimines using redox-active esters under blue light. This mild and efficient protocol demonstrates its utility as a versatile synthetic tool, especially for medicinal chemists.
We report a diastereoselective, photocatalyst-free decarboxylative alkylation of (hetero)aryl sulfinimines using redox-active esters under blue light. High yields and diastereoselectivities can be achieved under mild conditions, and we demonstrate its utility as a synthetic method, especially for medicinal chemists.
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