4.7 Article

Acid-Promoted Iso-Nazarov Cyclization of Conjugated trans- Dienones and Dienals for the Synthesis of 2-Cyclopentenones

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 87, Issue 20, Pages 13469-13479

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c01783

Keywords

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Funding

  1. Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET) [PUE-2016, PIP 2021-2023-1045]
  2. Agencia Nacional de Promocion Cientifica y Tecnologica (ANPCyT) [PICT-2017-2694, PICT-2018-4150]
  3. Agencia Santafesina de Ciencia, Tecnologia e Innovacion (ASACTEI) [AC-2015-00005]
  4. Universidad Nacional de Rosario [BIO 580, UNR-80020180300024UR]
  5. CNRS
  6. Ecole Polytechnique
  7. UPSaclay

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This article presents a synthetic strategy for constructing 2-cyclopentenones through acid-promoted cyclization of all-trans linearly conjugated dienones and dienals.
The acid-promoted cyclization of all-trans linearly conjugated dienones and dienals constitutes a synthetic strategy for the construction of 2-cyclopentenones.

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