Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume -, Issue -, Pages -Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c01659
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Funding
- National Natural Science Foundation of China
- Applied Basic Research Project of Yunnan Province
- Department of Education of Yunnan Province
- Yunnan Provincial Key Laboratory Construction Plan Funding of Universities
- [21961045]
- [21572198]
- [2017FA004]
- [2018FB021]
- [2019Y0198]
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A wide range of chiral 3-amino-2-oxindoles were successfully synthesized with high optical purities through the enantioselective Friedel-Crafts addition of naphthols with isatin-derived ketimines using H8-BINOL-derived chiral biaryl phosphoric acid as the catalyst.
The enantioselective Friedel-Crafts addition of naphthols with isatin-derived ketimines was developed with H8- BINOL-derived chiral biaryl phosphoric acid. A wide range of isatin-derived ketimines and naphthols were successfully applied and gave a series of chiral 3-amino-2-oxindoles in excellent yields with high optical purities.
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