4.7 Article

Cholesteric liquid crystal-based printing inks with temperature and reflection angles response properties

Journal

JOURNAL OF MOLECULAR LIQUIDS
Volume 363, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.molliq.2022.119905

Keywords

Printing inks; Cholesteric liquid crystals; Temperature; Reflection angle

Funding

  1. National Natural Science Founda- tion of China [21861040]
  2. Scientific Research Fund project of Ningde Normal University [2020Z02]
  3. Natural Science Foundation of Jiangsu Province [BK20190157]
  4. Science and Technology Project of Xuzhou [KC21039, KC21286]

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Printable cholesteric liquid crystal-based printing inks with excellent stability and a wide range of color patterns have been fabricated on a black substrate.
Cholesteric liquid crystals (CLCs) are usually used in printing inks, and have a wide range of potential applications. Here, printable cholesteric liquid crystal-based printing inks have been fabricated. First, a series of cyclic side-chain CLC photonic inks containing chiral 4-(((40-(allyloxy)-[1,10-biphenyl]-4-yl)ox y)carbonyl)phenyl (2-isopropyl-5-methylcyclohexyl) succinate (M1) and chiral 4-(4-(4-Menthyloxy-4-o xobutanoyloxy)benzoyloxy)phenyl 4-allyloxybenzoate (M2), denoted as N1-N5, were obtained via graft copolymerization. The cyclic side-chain CLCs exhibit structural colors caused by dual photonic bandgaps, resulting in a wide variety of colors. Subsequently, the color patterns of CLC printing inks were fabricated by coating the CLCs on the black substrate by screen printing. The color patterns of CLC printing inks have shown excellent stability at room temperature for more than 1 year. CO 2022 Published by Elsevier B.V.

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