Journal
JOURNAL OF MEMBRANE SCIENCE
Volume 661, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.memsci.2022.120932
Keywords
Cellulose nanocrystals; Ultrafiltration; Electrostatic interactions; Controlled deposition; Shear alignment
Categories
Funding
- Scientific and Technological Council of Turkey (TUBITAK) [119M828]
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Precise control over membrane performance can be achieved by tuning fabrication parameters, such as ionic strength and pH of suspensions, as well as the alignment and morphology of nanocrystals. The rejection and separation efficiency of the membranes can be adjusted by altering the electrostatic interactions between nanocrystals during deposition.
Precise control over membrane performance by tuning fabrication parameters is highly desirable. We developed ultrafiltration membranes by depositing cellulose nanocrystals (CNCs) on a porous support via tangential flow filtration, followed by irreversibly coagulating the deposited layer by permeating highly concentrated AlCl3 solution. By varying electrostatic interactions between nanocrystals during deposition, via varying ionic strength and pH of CNC suspensions, membrane performance was tuned. Increasing NaCl concentration of CNC sus-pensions from 0 to 50 mM increased Blue Dextran (5 kDa) rejection from 93% to 98.5% at high tangential flowrate and from 82% to 98% at low tangential flowrate. For membranes fabricated at high tangential flowrate, beta-lactoglobulin (18 kDa) rejections increased from 94% to 98% when NaCl concentration increased from 0 to 25 mM. Increasing pH of CNC suspensions also increased probe molecule rejections, implying smaller interparticle distance between CNCs in the deposit layer. Pure water permeance of membranes were comparable to com-mercial membranes of similar separation properties. Polarized optical microscopy analyses showed that align-ment of CNCs and their aggregates, or tactoids, affect the morphology of CNC deposits. In all cases, decreasing electrostatic repulsion between nanocyrstals increased rejection regardless of CNC alignment, which provides a simple parameter for tuning CNC membrane performance.
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