Synthesis of adjustable {312}/{004} facet heterojunction MWCNTs/Bi5O7I photocatalyst for ofloxacin degradation: Novel insights into the charge carriers transport

Multi-wall carbon nanotubes (MWCNTs) with high electrical conductivity are commonly accounted as the ideal additives to enhance the charge surface migration efficiency in photocatalysis. Theoretically, the MWCNTs-modified binary photocatalysts have potential for the change of nanocrystal structure. Herein, we reports an adjustable {312}/{004}facet heterojunction MWCNTs/Bi5O7I nanocomposite. Interestingly, the synergistic effect of {312}/{004}facet heterojunction and MWCNTs can effectively accelerate the spatial charge carriers transport. A novel {312}/{004}facet S-scheme pathway was proven to be the dominated pathway for the enhancement of spatial charge carriers. As a result, the MWCNTs-{312}/{004}Bi5O7I composites exhibited superior photocatalytic oxidation efficiency for a representative antibiotics ofloxacin photodegradation. Density functional theory (DFT) calculation and LC-MS/MS analysis confirmed that the possible dealkylation and oxidation pathways could be found in OFL degradation. This work provides novel insights for the relationship between charge carrier transport and facet structure-property.

Automated summary

This study reports an adjustable {312}/{004} facet heterojunction MWCNTs/Bi5O7I nanocomposite, which exhibits superior photocatalytic oxidation efficiency by accelerating the transport of spatial charge carriers. This work provides novel insights into the relationship between charge carrier transport and facet structure-property.