4.5 Article

Gas-Sensitive Properties of ZnO/ZnCo2O4 Made from Sodium Citrate Against Formaldehyde

Journal

JOURNAL OF ELECTRONIC MATERIALS
Volume 51, Issue 12, Pages 7009-7019

Publisher

SPRINGER
DOI: 10.1007/s11664-022-09930-y

Keywords

Formaldehyde; sensor; ZnO-ZnCo2O4; spinel

Funding

  1. Key Research and Development Program of Zhejiang Province [2019C04003]

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This study successfully prepared ZnCo2O4 material for formaldehyde gas sensors by varying the addition of sodium citrate, and found that ZnO-ZnCo2O4 showed better gas sensitivity and selectivity. These results provide important foundational knowledge for the application of spinel oxide materials in the field of gas sensors.
Since cobalt-containing spinel oxides have good prospects for the detection of toxic gases, they also have great potential for applications in the field of gas sensors. However, ZnCo2O4 -based gas sensors have the disadvantages of low response values and poor selectivity in formaldehyde detection. In this study, we attempted to prepare formaldehyde gas sensors by varying the addition of sodium citrate for hydrothermal synthesis of ZnCo2O4. During the fabrication process, it was found that an appropriate amount of sodium citrate content could produce ZnO on the surface of ZnCo2O4 , and that the gas sensitivity of ZnO-ZnCo2O4 to formaldehyde was better compared to that of pure ZnCo2O4. The sensor has a response rate of 17 at 20 ppm formaldehyde at 200 degrees C. It also has good selectivity, repeatability, and stability. These results can provide foundational knowledge for the implementation of spinel oxide materials in the field of gas sensors.

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