Journal
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
Volume 26, Issue 6, Pages 1174-1197Publisher
SPRINGER
DOI: 10.1007/s10904-016-0378-7
Keywords
Copper; Thioether; Luminescence; Coordination polymer; Cluster; MOF
Categories
Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Fonds de recherche du Quebec-Nature et technologies (FRQNT)
- Centre Quebecois pour les Materiaux Fonctionnels (CQMF)
- et the Centre des materiaux optiques et photoniques de l'Universite de Sherbrooke (CEMOPUS)
- CNRS
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This mini-review surveys 23 structures of 3D coordination polymers built upon mono-, di- as well as cyclic and acylic polythioethers. An emphasis is put on the Secondary Building Units (SBU) and the physical properties. Importantly, the key feature is that the dominant SBU is not the rhomboid (Cu2X2S4), but an inorganic polymer containing at least the chain of the type (CuX) (n) . In the latter type of SBU, these chain formations are observed for X = I, but predominantly for X = CN. In addition, a large portion of the surveyed materials exhibit rich photophysical properties, but on several occasions, these materials exhibit properties often attributed to MOFs, mainly solvent exchange.
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