4.8 Article

Tetraphosphite ligand for ultrafast isomerization-hydroformylation of C4 raffinate under mild conditions

Journal

JOURNAL OF CATALYSIS
Volume 413, Issue -, Pages 388-397

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2022.06.009

Keywords

Isomerization; Hydroformylation; C4 raffinate; Tetraphosphite; N-valeraldehyde

Funding

  1. Technology Innovation Committee of Shenzhen [JCYJ20170817104824122]
  2. Guangdong Provincial Key Laboratory of Catalysis [2020B121201002]

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This article reports the application of a novel tetraphosphite ligand in the ISO-HF of C4 Raffinate. The ligand showed high turnover frequencies and regioselectivities in the reaction, and demonstrated excellent durability in large-scale continuous reactors.
Ultrafast linear selective isomerization-hydroformylation (ISO-HF) tandem reaction under mild conditions remains a challenge. Herein, a novel tetraphosphite ligand (TBTP) and its application in ISO-HF of C4 Raffinate were reported. Based on a biphenol-2,2',6,6'-tetraol with sterically demanding tert-butyl substituents, TBTP can be readily prepared by the reaction of biphenyl phosphorchloridite and tetraol in kilogram scale. The structural and coordinating features of this ligand and its rhodium complex were studied by XRD, NMR and DFT calculations. This tetraphosphite ligand showed high turnover frequencies and regioselectivities in the rhodium-catalyzed ISO-HF of trans-, cis-2-butene. Such hydrolytically stable ligand was successfully applied in the ISO-HF of etherified C4 feed under a mild condition (65 degrees C, 7 bar syngas, TOF up to 1574 h(-1), similar to 95% linear selectivity). An over-14-day durability test that was operated in two 5-L continuously stirred-tank reactors (CSTRs) in series delivered 79 kg n-valeraldehyde for the manufacture of C10 plasticizer DPHP. (C) 2022 Elsevier Inc. All rights reserved.

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