4.6 Article

A high-speed, salt-free, and dyebath-recyclable circular coloration technology inspired by mussel bionic

Journal

JOURNAL OF APPLIED POLYMER SCIENCE
Volume 139, Issue 47, Pages -

Publisher

WILEY
DOI: 10.1002/app.53178

Keywords

coatings; dyes; pigments; surfaces and interfaces; textiles

Funding

  1. Key Research and Development Project of Shandong Province [ZR2021ZD27]
  2. Youth Innovation Team Development Plan of Universities in Shandong Province [2021KJ056]
  3. Natural Science Foundation of Shandong Province [ZR2020ME082, ZR2019BB030]
  4. Science Fund of Shandong Laboratory of Advanced Materials and Green Manufacturing (Yantai) [AMGM2021F05]
  5. Program for Scientific Research Innovation Team in Colleges and Universities of Jinan [2018GXRC006]

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In this study, an eco-friendly and universal dyeing technology was developed using a polymer of catechol and polyethyleneimine as a dye. The dyed fabrics showed excellent fastness characteristics and antibacterial properties, making this technology highly promising for various applications.
With the current situation of high-energy consumption and high pollution in the textile industry, developing an eco-friendly and universal dyeing technology is urgently required. Towards this goal, in this study, the dyeing technology with room temperature, salt-free, zero release, and rapid cycle dyeing for 20 min was realized using a polymer of catechol and polyethyleneimine as a dye. The dyed fabrics exhibited washing, rubbing, and perspiration fastness characteristics for practical needs, mainly attributing to the hydrogen bonding and pi-pi interaction between the dye molecules and the fabrics. Benefiting from the unique dyeing technology, the dyed fabrics show excellent leveling properties and adjustable chromaticity. Importantly, the mussel-inspired coating strategies are universally applicable, so the dyeing technology can be applied to various fabrics. Consequently, the environmentally friendly dyeing process based on low-cost catecholamine polymers as a dye will have a broad application prospect in the printing and dyeing industry. Moreover, the antibacterial tests showed that dyed cotton cloth, mulberry silk, and polyester fabrics all have favorable antibacterial properties, especially dyed mulberry silk fabrics have a greater than 90% bacterial reduction rate for both Escherichia coli and Staphylococcus aureus.

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