Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 915, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2022.165378
Keywords
Fe-rich phase; Al-Si alloy; Solidification; X-ray tomography; X-ray radiography; Mechanical property
Categories
Funding
- National Natural Science Foundation of China [52074131, 52104373]
- Basic Foundation and Applied Foundation Program of Guangdong Province, China [2020B1515120065, 2019A1515110270]
- Science and Technology Plan Program of Guangdong Province, China [2015B090926013, 2019B090905009]
- BL13HB beamline in the Shanghai Synchrotron Radiation Facility (SSRF) , China [2020-SSRF-PT-011937, 2020-SSRF-PT-011898]
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The effect of Mn addition on the formation and properties of Fe-rich phases in Al-7Si-1.2Fe alloys was systematically studied. The results show that Mn addition changes the morphology of the Fe-rich phase and increases the three-dimensional structure of the phase with increasing Mn content. Excessive Mn addition leads to the formation of large Fe-rich phases, resulting in a reduction in the elongation properties of the alloys.
The plate-like Fe-rich intermetallics phases in the recycled Al-Si alloys significantly deteriorate the mechanical properties. In this study, the effect of Mn addition on Fe-rich phases formation and the properties of the Al-7Si-1.2Fe alloys were systematically studied by optical microscopy, scanning electron microscopy, differential scanning calorimetry, thermodynamic calculations, synchrotron X-ray radiography and tomography. The results show that with the addition of Mn, the two-dimensional (2D) morphology of the Fe-rich phase change from plate-like to Chinese-script and star-like. The synchrotron X-ray tomography results indicate that the three-dimensional (3D) morphology of Fe-rich phases change from interconnected platelike to separated hollow polyhedron with increasing Mn content. The in-situ synchrotron X-ray radiography results reveal that the formation temperature, size, and area fraction of the primary Fe-rich phase in the Al7Si-1.2Fe-1.09Mn alloy gradually decreased, but the number density increased as the cooling rate increased. The thermodynamic calculation results indicate that beta-Al5FeSi could be eliminated when the Mn content exceeded 1.06%, which was consistent with the experimental results. However, excessive Mn addition caused the formation of large primary Fe-rich phases, resulting in a significant reduction in the elongation of the alloys. Reducing the equilibrium partition coefficient difference of Mn and Fe and reducing the formation of primary Fe-rich phases with high Mn/Fe ratios are good strategies to neutralize the negative effect of Fe-rich phases. (C) 2022 Elsevier B.V. All rights reserved.
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