4.7 Article

High-performance magnesium alloy with multi-element synergistic strengthening: Design, microstructure, and tensile properties

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 918, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2022.165746

Keywords

Multi-element Mg alloys; Composition design; Microstructure; Tensile mechanical properties

Funding

  1. National Natural Science Foundation of China [51974082, 51901037]
  2. State Key Laboratory of Baiyunobo Rare Earth Resource Researched and Comprehensive Utilization [2021H2279]

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This study designed multi-element synergistic strengthening Mg alloys inspired by the concept of high entropy alloys, and found the optimal composition of Mg-1.4Sn-0.93Zn-0.83Ca-0.67Mn-0.39Al (AXMZT-5), which exhibits high strength and elongation. The fine-grained structure, residual dislocations, and uniformly distributed nanoparticles were identified as contributing factors to the high yield strength of the alloy.
Given the limitations of the phase diagram method and the blindness of the trial-and-error method in the composition design of multi-element Mg alloys, the design of multi-element synergistic strengthening Mg alloys was conducted in this work inspired by the design concept of high entropy alloys. Out of the requirement of low-cost and high-performance wrought Mg alloys, inexpensive Al, Ca, Mn, Zn and Sn were added in different ratios. The experimental alloys were prepared by casting and one-step hot extrusion. The optimal composition was Mg-1.4Sn-0.93Zn-0.83Ca-0.67Mn-0.39Al (named as AXMZT-5) showing the best combination of strength and elongation. The microstructure of extruded pure Mg and the AXMZT-5 alloy was studied in detail to reveal the reason for the excellent yield strength (YS) of AXMZT-5 up to 280 MPa, 197% higher than that of pure Mg. Fine-grained structure, residual dislocations, and relatively uniformly distributed nanoparticles of CaMgSn, Ca-2(Mg, Al)(6)Zn-3, and Al-Mn phases are attributed to the high YS. In addition, the sharp (0001) basal fiber texture from the un-recrystallized grains in the bimodal microstructure also contribute to the increase of strength. A large number of fine recrystallized grains make the AXMZT-5 alloy exhibit a ductile-dominated fracture mode, which results in its excellent elongation. (C) 2022 Elsevier B.V. All rights reserved.

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