4.7 Review

Degradation mechanism and modeling study on reversible solid oxide cell in dual-mode d A review

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 47, Issue 89, Pages 37895-37928

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2022.08.240

Keywords

Degradation; rSOCs; Dual mode; Modelling work

Funding

  1. National Key Research and Development Project of China [2018YFB1502204]
  2. Ningbo Innovation team grant [Ningbo[2017]74]
  3. Ningbo major special projects of the Plan Science and Technology Innovation [2018B10048]
  4. Shanghai Frontiers Science Center of Full Penetra-tion Far-reaching Offshore Ocean Energy and Power
  5. Fishery Engineering and Equipment Innovation Team of Shanghai High-level Local University

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This article provides a comprehensive review of degradation issues in reversible solid oxide cells (rSOCs), covering research on degradation in both single and dual modes, solution strategies for material development and optimization, and modeling work to predict degradation behaviors. The article emphasizes the connections and differences in degradation between single and dual modes, and proposes perspectives for improving reversibility and durability in long-term applications.
Degradation issues are major obstacles to commercializing reversible solid oxide cells (rSOCs), which are promising energy production/storage devices. This article organizes and comprehensively reviews the current understanding of degradation issues in rSOCs, which range from fundamental research on degradation in both single and dual modes to solution strategies for both bifunctional material development and preparation/manufacture optimization, as well as modelling work performed at different scales to predict the degradation behaviours of rSOCs. It proposes perspectives for state-of-the-art work on degradation and solutions highlighted in reversible operation. An in-depth review of the links and differences for degradation in single and dual modes is also emphasized. The trade-offs between various degradation issues for rSOCs must be considered by further understanding the degradation mechanisms in dual-mode operation to improve the reversibility/ durability of long-term applications.(c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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