A simple method for preparing ThO2 ceramics with high density

A simple and effective method for preparing ThO2 ceramics with high density has been proposed. It mainly includes a positive precipitation approach and a conventional sintering process. The SEM images and laser particle size analysis show that the prepared powder exhibits a round-plated shape with a uniform and narrow particle size distribution, which is the key to the densification sintering of ThO2 ceramics. The XRD analyses confirm that the ThO2 ceramics sintered at 1590 degrees C were composed of cubic fluorite phase. The effect of sintering temperature on the density of ThO2 ceramics was also investigated, and a relative density higher than 95% were achieved after sintering at 1590 degrees C for 6 h in an air atmosphere. Moreover, the Vickers hardness was up to 8.49 GPa, the average linear expansion coefficient within 40-800 degrees C was low to 10.97 x 10(-6)/K, and the thermal conductivity and the thermal diffusivity were both higher than most of traditional ceramic materials (16.94-5.86 W/m K and 7.28-1.28 mm(2)/s, respectively, within the temperature range of 25-800 degrees C). The previous great performances are closely related to its high density, which enables it to be a great candidate for nuclear fuels and other potential application fields.

Automated summary

A simple and effective method for preparing high-density ThO2 ceramics was proposed, involving a positive precipitation approach and a conventional sintering process. The prepared powder exhibited a round-plated shape with a uniform and narrow particle size distribution. The resulting ceramics demonstrated high density, low linear expansion coefficient, and high thermal conductivity and diffusivity.