Cooperative Spin Crossover above Room Temperature in the Iron(II) Cyanoborohydride-Pyrazine Complex

Hysteretic spin crossover in coordination complexes of 3d-metal ions represents one of the most spectacular phenomena of molecular bistability. In this paper we describe a self-assembly of pyrazine (pz) and Fe(BH3CN)2 that afforded the new 2D coordination polymer [Fe(pz)2(BH3CN)(2)]. It undergoes an abrupt, hysteretic spin crossover (SCO) with a T1/2 of 338 K (heating) and 326 K (cooling) according to magnetic susceptibility measurements. Mo''ssbauer spectroscopy revealed a complete transition between the low-spin (LS) and the high-spin (HS) states of the iron centers. This LS-to-HS transition induced an increase of the unit cell volume by 10.6%. Meanwhile, a modulation of multiple [C-H delta+...H delta--B] dihydrogen bonds stimulates a contraction in direction c (2.2%). The simplicity of the synthesis, mild temperatures of transition, a pronounced thermochromism, stability upon thermal cycling, a striking volume expansion upon SCO, and an easy processability to composite films make this new complex an attractive material for switchable components of diverse applications.

Automated summary

This paper describes a new 2D coordination polymer with hysteretic spin crossover behavior, which exhibits attractive features such as thermochromism, stability upon thermal cycling, and significant volume expansion during the spin crossover process.