Journal
INORGANIC CHEMISTRY
Volume 61, Issue 43, Pages 16997-17001Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.2c03266
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Funding
- National Natural Science Foundation of China [22122106, 22071158, 21971171]
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The novel antimony(III)-based phosphite, SbHPO3F, with a unique two-dimensional van der Waals layered structure, has desirable optical properties and potential applications as a UV birefringent material.
A novel antimony(III)-based phosphite, SbHPO3F, featuring a unique two-dimensional (2D) van der Waals layered structure, has been successfully designed and synthesized via the simultaneous employment of optically active moieties including SbO3F seesaw and tetrahedral HPO3 groups. Its optimized layered arrangement formed by the alternating connection of 4-membered rings (4-MRs) and 8-MRs endows the title compound with desirable optical properties including a large birefringence and short ultraviolet (UV) cutoff edge, implying that it is a potential UV birefringent material.
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