4.7 Article

Durable and biocompatible antibacterial N-halamine membranes based on cellulose carbamate

Journal

INDUSTRIAL CROPS AND PRODUCTS
Volume 187, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.indcrop.2022.115518

Keywords

Cellulose carbamate; N-halamine; Antibacterial; Durable and biocompatible

Funding

  1. National Natural Science Foundation of China [52005275]
  2. National Key Research and Development Program of China [2020YFC1910300]
  3. State Key Laboratory of Bio-Fibers and Eco-Textiles (Qingdao University) [ZKT43]

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In this study, an antibacterial N-halamine regenerated cellulose carbamate membrane (RCCM-Cl) was manufactured and evaluated. The RCCM-Cl showed remarkable antibacterial activity, maintained certain mechanical properties and transparency, and exhibited excellent performance in terms of cell compatibility, rechargability, and stability.
Increasing attention had been paid to the antibacterial and safety properties of membrane materials. The cellulose carbamate membrane (RCCM) without antibacterial properties would limit its applications in the food packaging industry. Herein, the antibacterial N-halamine regenerated cellulose carbamate membrane (RCCM-Cl) was manufactured by sodium hypochlorite solution treating the inherent amide of RCCM. The chemistry and mechanics properties of RCCM and RCCM-Cl were investigated. The antibacterial properties, cell compatibility, rechargeability and durability stability of RCCM-Cl were evaluated. Results demonstrated that the functional RCCM-Cl exhibits remarkable antibacterial activity which could sterilize Escherichia coli and Staphylococcus aureus within 1 min in the first contact period. The breaking strength, elongation at breaking, and transparency of RCCM-Cl retained 148.6 MPa, 8.1%, and 94%, respectively. In addition, antibacterial RCCM-Cl with active chlorine content exhibits excellent cell compatibility, regenerability, storage stability and stability in water.

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