Journal
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 61, Issue 40, Pages 14847-14858Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.2c02748
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This study explored the synthesis process and kinetics of the esterification reaction between methanol and sorbic acid catalyzed by deep eutectic solvents (DESs). A green DES composed of choline chloride (ChCl) and p-toluene sulfonic acid monohydrate (PTSA) was successfully prepared. The process was optimized using the response surface methodology, and the effects of various parameters on the conversion of sorbic acid were evaluated. The kinetic data and chemical equilibrium compositions of the reaction were measured using ChCl-1.38PTSA as a catalyst, and the thermodynamic data were calculated. A pseudohomogeneous model based on activity was used to describe the reaction kinetics, and the model showed good fit with the experimental data. The stability and recyclability of ChCl-1.38PTSA were also determined.
The synthesis process and kinetics of the ester-ification of methanol with sorbic acid catalyzed by deep eutectic solvents (DESs) were explored in this study. A series of green DESs composed of choline chloride (ChCl) and p-toluene sulfonic acid monohydrate (PTSA) were successfully prepared. Design and optimization of the process were conducted using the response surface methodology with Box-Behnen design. The influences of the value of z (z is the molar ratio of PTSA to ChCl), catalyst loading, methanol/sorbic acid molar ratio, and temperature on the conversion of sorbic acid were evaluated. Using ChCl-1.38PTSA as a catalyst, the kinetic data and chemical equilibrium compositions of the esterification were measured at a temperature range of 340.15-355.15 K. The UNIFAC model was utilized to estimate the equilibrium constants, and the thermodynamic data (Delta rH0, Delta rS0, Delta rG0) of the esterification reaction were calculated as well. The pseudohomogeneous model based on activity was then adopted to describe the reaction kinetics and the model fitted well with the experimental data. The activation energy of the forward and reverse reaction were calculated. In addition, the activity of ChCl-1.38PTSA declined not obviously after five cycles, suggesting that ChCl-1.38PTSA has good stability and recyclability.
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