4.7 Article

Atmosphere-Snow Exchange Explains Surface Snow Isotope Variability

Journal

GEOPHYSICAL RESEARCH LETTERS
Volume 49, Issue 20, Pages -

Publisher

AMER GEOPHYSICAL UNION
DOI: 10.1029/2022GL099529

Keywords

stable water isotopes; ice cores; snow-atmosphere exchange; Greenland Ice Sheet; paleoclimate reconstruction; EGRIP

Funding

  1. European Research Council (ERC), European Union [759526]
  2. A. P. Moller Foundation, Denmark
  3. University of Copenhagen, Denmark
  4. US National Science Foundation, USA
  5. Office of Polar Programs, USA
  6. Alfred Wegener Institute, Germany
  7. Helmholtz Centre for Polar and Marine Research, Germany
  8. National Institute of Polar Research and Arctic Challenge for Sustainability, Japan
  9. University of Bergen, Norway
  10. Trond Mohn Foundation, Norway
  11. Swiss National Science Foundation, Switzerland
  12. French Polar Institute, France
  13. Institute for Geosciences and Environmental research, France
  14. University of Manitoba, Canada
  15. Chinese Academy of Sciences, China
  16. Beijing Normal University, China
  17. European Research Council (ERC) [759526] Funding Source: European Research Council (ERC)

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Research suggests that vapor-snow exchange influences surface snow isotopes during the summer, leading to biases in ice core records. This finding highlights the importance of considering the impact of vapor-snow exchange on signals when reconstructing paleoclimate from isotope records.
The climate signal imprinted in the snow isotopic composition allows to infer past climate variability from ice core stable water isotope records. The concurrent evolution of vapor and surface snow isotopic composition between precipitation events indicates that post-depositional atmosphere-snow humidity exchange influences the snow and hence the ice core isotope signal. To date, however, this is not accounted for in paeleoclimate reconstructions from isotope records. Here we show that vapor-snow exchange explains 36% of the summertime day-to-day delta O-18 variability of the surface snow between precipitation events, and 53% of the delta D variability. Through observations from the Greenland Ice Sheet and accompanying modeling we demonstrate that vapor-snow exchange introduces a warm bias on the summertime snow isotope value relevant for ice core records. In case of long-term variability in atmosphere-snow exchange the relevance for the ice core signal is also variable and thus paleoclimate reconstructions from isotope records should be revisited.

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