Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume 2022, Issue 30, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.202200397
Keywords
Dysprosium; Lanthanides; Single-molecule magnet; Slow relaxation; Tetraphenylborate
Categories
Funding
- Russian Science Foundation [17-73-30036]
- Ministry of Science and Higher Education of the Russian Federation
- University of Montpellier
- CNRS
- Institut Universitaire de France
Ask authors/readers for more resources
The synthesis and structures of two base-free alkoxide dysprosium(III) complexes are reported, and the magnetic properties of one of the complexes are investigated, revealing the occurrence of a field-induced slow relaxation of the magnetization.
We report the synthesis and structures of two base-free alkoxide dysprosium(III) complexes of formula [Dy(L-1)(2) (mu-eta(6):eta(1)-Ph)(2)BPh2]center dot CH2Cl2 (1) and [Dy(L-2)(2)(mu-eta(6):eta(1)-Ph)(2)BPh2]center dot 3(C7H8) (2) featuring a tetraphenylborate binding (L-1-2,6-dibenzhydryl-4-(tert-butyl)phenolate, L-2-tri(naphtalen-1-yl)methanolate). Investigations of the magnetic properties for 1 in line with theoretical calculations reveal the occurrence of a field-induced slow relaxation of the magnetization.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available