Direct evidence of CO2 softening effects on coal using nanoindentation

Sequestration of carbon dioxide (CO2) in deep coal seams has been identified as a promising technique to mitigate global warming with added benefit of enhancing coalbed methane recovery. Understanding coal structure and its reactivity with injected CO(2 )is important for CO(2 )sequestration in coal. Despite the long-standing hypothesis, there is no direct evidence of softening effects of CO(2 )on coal due to CO2-coal interactions. Here, we used optical microscopy and nanoindentation to study changes in microstructures and nanoscale mechanical properties of untreated and CO2-treated anthracite coal. Microscopic images indicated coal surface cracked after short-term treatment and then became highly wrinkled and distorted after long-term treatment. These changes refiect that CO(2 )dissolves in the macromolecular network and acts as a solvent allowing a rearrangement of the network. Nanoindentation directly confirmed the softening effects of CO(2 )on nanoscale mechanical properties, including Young's modulus, hardness, and fracture toughness. Interestingly, all these changes were reversible to some extent after removing CO(2 )from coal. These findings provide new evidence for clarifying the polymeric macromolecular structure of coal and directly demonstrated the softening effects of CO(2 )on the macromolecular structure. (C) 2022 Elsevier Ltd. All rights reserved.

Automated summary

This study reveals the effects of CO2 on the micro and nano-scale properties of coal, confirms the softening effects of CO2 on coal, and indicates that these changes are reversible to some extent.