Journal
ELECTROCHIMICA ACTA
Volume 426, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2022.140781
Keywords
Dilute solutions; Electrolyte solutions; Ideal solutions; Incompressibility; Steric effects
Categories
Funding
- National Sci- ence Foundation [OISE-1545857]
Ask authors/readers for more resources
Solutions are important components of natural and technological systems. We argue that in addition to the classical hypotheses of ideality and diluteness, solutions must also be incompressible and have small volumetric fractions of solutes. We propose the name "ideal-dilute-incompressible solutions" for this new cornerstone of solution theory.
Solutions are crucial components of natural and technological systems. Two of the classical hypotheses in so-lution theory are those of ideality and diluteness, which are used in the literature to assign to the solutes an activity equal to that of perfect gases and derive Fick's law of diffusion. Here, we argue that these hypotheses are not sufficient for these purposes. Two more hypotheses are missing: the solution must be incompressible and the volumetric fractions of solutes must be small. We propose to name this new cornerstone of solution theory ideal -dilute-incompressible solutions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available