4.7 Article

Effect of temperature on the preferential intergranular oxidation susceptibility of thermally-treated Alloy 600

Journal

CORROSION SCIENCE
Volume 207, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2022.110565

Keywords

Alloy 600; Preferential Intergranular Oxidation; Diffusion-Induced Grain Boundary Migration; AEM

Funding

  1. EPSRC [EP/JO21172/1]
  2. NNUMAN

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Testing thermally-treated Alloy 600 coupons in different environments showed that the consumption of intergranular carbides can reduce stress corrosion cracking precursors events, providing valuable insights into the corrosion resistance properties of alloy materials.
Thermally-treated Alloy 600 coupons were tested in pressurized water reactor simulated primary water at 320 ? and in high-pressure superheated steam at 400 ? to study the effect of a semi-continuous network of intergranular carbides on the stress corrosion cracking precursors events : preferential intergranular oxidation (PIO) and diffusion-induced grain boundary migration (DIGM). The intergranular carbides were partially consumed due to the environmental exposure, whereby the Cr released from the carbides contributed to the formation of the external oxide layer that limited both PIO and DIGM. The results were compared with previous studies in which similar coupons were exposed to H-2-steam.

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