Journal
COORDINATION CHEMISTRY REVIEWS
Volume 470, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2022.214706
Keywords
Chalcogenides; Three-dimensional frameworks; Nonlinear optics; Infrared; Structure -activity relationships
Categories
Funding
- National Natural Science Foun-dation of China [22175175, 21771179, 21901246]
- Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China [2021ZR118]
- Natural Science Foun-dation of Fujian Province [2019J01133]
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Second-order infrared nonlinear optical (IR-NLO) crystals have significant scientific and technological importance due to their ability to generate coherent tunable laser irradiation in the IR regions. Metal chalcogenides with three-dimensional frameworks have attracted extensive attention as important IR-NLO candidates. However, a comprehensive review of this IR-NLO family is currently lacking. In this review, the syntheses, crystal structures, and structure-activity relationships of over 200 non-centrosymmetric chalcogenides are systematically summarized and analyzed, providing guidance for the future exploration and design of novel IR-NLO 3D chalcogenide frameworks.
Second-order infrared nonlinear optical (IR-NLO) crystals are of great scientific and technological significance because of the ability to produce coherent tunable laser irradiation in the IR regions. Nowadays, the intrinsic problems in these traditional commercial IR-NLO crystals include AgGaS2, AgGaSe2, and ZnGeP2 have severely limited their further applications in modern laser technology, especially in the high-power and high-efficiency laser fields. Therefore, exploring novel IR-NLO candidates with excellent overall performance is the frontier and focus of related research fields. Notably, metal chalcogenides with three-dimensional (3D) frameworks have drawn extensive concern as a family of important IR-NLO candidates owing to their intriguing architectures and attractive optical properties. However, a comprehensive review on this IR-NLO family is absent to date. In this review, the reported metal chalcogenides are divided into six categories according to different types of filled cations, including (i) alkali-metal-based IR-NLO chalcogenides; (ii) alkaline-earth-metal-based IR-NLO chalcogenides; (iii) rare-earth-metalbased IR-NLO chalcogenides; (iv) lone-pair-cation-based IR-NLO chalcogenides; (v) polycation-based IR-NLO chalcogenides; and (vi) mixed-cation-based IR-NLO chalcogenides. The syntheses, crystal structures and the intrinsic structure-activity relationships for >200 non-centrosymmetric chalcogenides (including 7 crystal systems, 32 space groups and 51 representative compositions) have been systematically summarized and analyzed. Finally, some helpful guidance for the further exploration and design of novel IR-NLO 3D chalcogenide frameworks in the future is also provided. (c) 2022 Elsevier B.V. All rights reserved.
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