4.7 Article

Properties and mechanism of self-healing cement paste containing microcapsule under different curing conditions

Journal

CONSTRUCTION AND BUILDING MATERIALS
Volume 357, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.conbuildmat.2022.129410

Keywords

Cement repair materials; Microcapsule; Self -healing; Mechanical property; Pore structure

Funding

  1. Natural Science Foundation of China [U1906229]
  2. National key R& D project of China [2018YFB1600104]

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This paper investigated the properties and mechanism of grouting slurry and hardened paste body exposed to seawater using the grouting method to maintain the cracks of subsea tunnel lining concrete. The self-healing capacity was achieved by incorporating Urea-Formaldehyde/Epoxy (UF/E) microcapsules in the grouting materials. The results showed that the microcapsules had a negative effect on the mechanical properties and porosity, and the self-healing capacity varied with the dosage and pre-damage level.
This paper used the grouting method to maintain the cracks of subsea tunnel lining concrete, and the grouting materials was given the self-healing capacity by Urea-Formaldehyde/Epoxy (UF/E) microcapsules. The prop-erties and mechanism of grouting slurry and hardened paste body exposed to seawater were investigated. Firstly, the microcapsule was synthesized by means of an in-situ polymerization method. Then the fluidity and dispersion of microcapsules were investigated. Besides, the mechanical properties and pore structure of the composites were measured. Meanwhile, the strength and porosity recovery rates were calculated after pre-damage treatment. Finally, the self-healing mechanism of microcapsule was researched through Scanning Electron Microscope (SEM) and Energy Dispersive Spectrometer (EDS). The results indicated that the microcapsule had a negative effect on the mechanical properties and porosity. With the increasing microcapsule dosage, the self-healing capacity first increased and then decreased, and the highest capacity was achieved with 1% dosage. Mean-while, the self-healing capacity decreased with the increased pre-damage level. The SEM and EDS analysis showed that the microcapsule could repair the micro-cracks within the cement paste.

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