4.7 Article

Polyester polymer concrete modified by polyester fibers and gamma rays

Journal

CONSTRUCTION AND BUILDING MATERIALS
Volume 356, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.conbuildmat.2022.129278

Keywords

Polymer concrete; Polyester fibers; Marble; Gamma radiation; Compression; Crystallinity; Contact angle

Funding

  1. Autonomous University of the State of Mexico (UAEM) Toluca
  2. [UAEM 6228/2020CIB]

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Polymer concrete, which is made by mixing thermosetting resin and mineral aggregates, often has limited load-bearing applications due to its low ductility. To improve its mechanical properties, polymer fibers are sometimes added, but this can decrease performance. In this study, polyester fibers were added to polymer concrete and then irradiated with gamma rays. The results showed that the irradiated concrete had improved deformation, elasticity modulus, and compressive strength, which were attributed to the changes in marble crystallinity and the surface, chemical structure, and hydrophilicity of the polyester fibers caused by gamma radiation.
As is well-known, polymer concrete is manufactured by mixing a thermosetting resin, such as polyester, and mineral aggregates, such as silica sand and marble. Such concrete presents low levels of ductility, and its load -bearing applications are limited, which suggests using reinforcement materials as fibers for improvement. However, it is not common to add polymer fibers, since sometimes the mechanical performance decreases. Thus, polymer fibers need some kind of physical or chemical modification. One alternative consists of using high ionizing radiation, such as gamma rays. For these reasons, in this work, polyester fibers were added to polymer concrete produced with 30 wt% polyester resin and 70 wt% marble. Afterwards, concrete specimens were irradiated with gamma rays. Three marble particle sizes were used (7.1x10-3m, 14x10-3m and 23.6x10-3m), three fiber contents (0.1, 0.3 and 0.5 wt%) as well as three radiation doses (50, 100 and 150 kGy). Improvements of up to 35 % in the deformation, 29 % in the elasticity modulus and 10 % in the compressive strength, were obtained for irradiated concretes with polyester fibers. These mechanical features were related to the modifications produced by gamma rays on the marble crystallinity, as well as the surface, chemical structure, and hydrophi-licity of the polyester fibers.

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