Artificial and Semi-artificial Photosynthesis (AP and SAP) Systems Based on Metal-Organic Frameworks

Review Chemistry, Multidisciplinary

Two-Dimensional Metal-Organic Frameworks and Covalent Organic Frameworks

Qiankun Wang et al.

Summary: This review introduces the advantages and characteristics of 2D MOF/COF materials, discusses advanced strategies for preparing these materials, and summarizes their applications as well as the future challenges in this field.

CHINESE JOURNAL OF CHEMISTRY (2022)

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Review Chemistry, Inorganic & Nuclear

Engineering metal-organic frameworks for efficient photocatalytic conversion of CO2 into solar fuels

Chizoba Ezugwu et al.

Summary: Artificial photosynthesis is a promising technique for CO2 mitigation and solar energy conversion. Metal-organic frameworks (MOFs) are efficient photocatalysts with high surface area and flexible design capabilities for complex multicomponent systems. The review examines strategies for designing MOFs to convert CO2 into solar fuels efficiently, highlighting features as semiconductor photocatalysts and means to improve light-harvesting and CO2 adsorption.

COORDINATION CHEMISTRY REVIEWS (2022)

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Article Chemistry, Multidisciplinary

Water-Stable Nickel Metal-Organic Framework Nanobelts for Cocatalyst-Free Photocatalytic Water Splitting to Produce Hydrogen

Lifang Liu et al.

Summary: In this study, a novel water-stable metal-organic framework material was developed for efficient visible-light-driven photocatalytic water splitting without the need for cocatalysts. Exfoliated two-dimensional nanobelts showed enhanced charge separation and increased water reduction activity, leading to significantly improved hydrogen evolution performance.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

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Article Chemistry, Physical

Efficient Visible-Light Photoreduction of CO2 to CH4 over an Fe-Based Metal-Organic Framework (PCN-250-Fe3) in a Solid-Gas Mode

Jun-Rong An et al.

Summary: Researchers have developed a low-cost and photosensitive metal-organic framework (MOF) called PCN-250-Fe-3 using a facile hydrothermal method. This MOF exhibits highly efficient CO2 photoreduction under visible-light irradiation, outperforming most other MOF photocatalysts under solid-gas reaction conditions.

ACS APPLIED ENERGY MATERIALS (2022)

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Article Chemistry, Physical

Inter-clusters synergy in iron-organic frameworks for efficient CO2 photoreduction

Yu-Jie Wang et al.

Summary: This study demonstrates the precise encapsulation of dual-nuclear clusters into metal-organic frameworks to improve the activity and selectivity for CO2 reduction, achieving high formate generation activity and selectivity. The performance is much superior to most of the state-of-the-art MOF catalysts, attributed to inter-clusters synergy and cluster-framework cooperativity supported by DFT calculations and systemic experimental characterizations.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Article Chemistry, Multidisciplinary

Switching Excited State Distribution of Metal-Organic Framework for Dramatically Boosting Photocatalysis

Song Guo et al.

Summary: This study proposes a method to enhance the sensitizing ability of metal-organic frameworks by promoting electron transfer through hierarchical organization and multi-component synergy, leading to improved photocatalytic activity. This work provides a new approach for enhancing solar energy conversion through the molecular-level engineering of sensitizing centers.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Multidisciplinary

Bioinspired Metalation of the Metal-Organic Framework MIL-125-NH2 for Photocatalytic NADH Regeneration and Gas-Liquid-Solid Three-Phase Enzymatic CO2 Reduction

Gang Lin et al.

Summary: In this study, a Rh-complex-based electron transfer unit was chemically attached onto the linker of MIL-125-NH2, enabling photo-induced electron transfer for NADH regeneration. The formate dehydrogenase was deposited onto the membrane, creating an efficient reaction interface and enhancing formic acid yield.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Multidisciplinary

Charge Separation by Creating Band Bending in Metal-Organic Frameworks for Improved Photocatalytic Hydrogen Evolution

Chenxi Zhang et al.

Summary: This study demonstrates for the first time the band bending phenomenon in metal-organic frameworks (MOFs), achieved by integrating MOFs with metal oxides to form MOF composites. The resulting MOF composites show 56 to 42 times higher activities in photocatalytic H-2 production compared to pristine MOFs.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Engineering, Environmental

Long excited state lifetime of thermally activated delayed fluorescent photosensitizer integrated into Metal-organic framework enables efficient CO2 photoreduction

Binglin Bie et al.

Summary: The performance of metal-organic-framework-based photocatalysts can be enhanced by incorporating an organic thermally activated delayed fluorescence photosensitizer with a non-noble zinc node. This improvement leads to a longer excited state lifetime and efficient charge transfer, resulting in high efficiency CO2 photoreduction.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Multidisciplinary

Coupling Ruthenium Bipyridyl and Cobalt Imidazolate Units in aMetal-Organic Framework for an Efficient Photosynthetic OverallReaction in Diluted CO2

Ning-Yu Huang et al.

Summary: This study discovers a method for photocatalytic reduction of CO2 using water as the reductant under visible light. By incorporating classic photosensitive and catalytic units into a metal-organic framework, efficient photocatalytic CO2 reduction is achieved. The photocatalyst exhibits strong CO2 adsorption ability and high CO selectivity.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

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Article Chemistry, Physical

Synergy Effect between Facet and Zero-Valent Copper for Selectivity Photocatalytic Methane Formation from CO2

Yu Deng et al.

Summary: This study reveals that the (111) facet of Cu2O is the origin of selectivity for CH4 formation in photocatalytic CO2 reduction. Decorating the surface of Cu2O-111 with zero-valent copper further enhances the yield and selectivity. The results provide a promising idea for designing Cu2O catalysts for the conversion of CO2 into high-value-added hydrocarbon products with high activity and selectivity.

ACS CATALYSIS (2022)

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Article Engineering, Environmental

Constructing crystalline redox catalyst to achieve efficient CO2 photoreduction reaction in water vapor

Xiao-Xin Li et al.

Summary: In this study, a crystalline overall reaction catalyst, RO-4, is constructed to achieve efficient artificial photosynthesis for CO2 conversion. The catalyst allows easy transfer of photogenerated electrons between redox clusters, leading to high CO production activity and O2 release. The research uncovers the related reaction intermediates and CO2 photoreduction mechanism.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Multidisciplinary

Photocatalytic Carboxylation of Phenyl Halides with CO2 by Metal-Organic Frameworks Materials

Lina Su et al.

Summary: In this work, important commercial pharmaceutical intermediates, phenylpropionic acid compounds, were successfully obtained by catalyzing the reaction of carbon dioxide with phenyl halides using MOF-5. The influence of temperature, pressure, catalyst type, and light on the reaction was investigated, reaching a 90.3% selectivity towards fluorophenylpropionic acid. The catalysts were effective for varied benzyl compounds containing different substituent groups, and remained stable and active after three cycles.

CHINESE JOURNAL OF CHEMISTRY (2021)

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Article Multidisciplinary Sciences

Precise fabrication of single-atom alloy co-catalyst with optimal charge state for enhanced photocatalysis

Yating Pan et al.

Summary: Metal-organic framework (MOF) stabilized bimetallic Pd@Pt nanoparticles with adjustable Pt coordination environment and controlled structure from core-shell to single-atom alloy (SAA) have been fabricated. It was found that Pt surface charge regulation can be achieved by changing its coordination environment and the structure of the Pd@Pt co-catalyst, redistributing the charge between Pd and Pt. The optimized Pd-10@Pt-1/MOF composite, featuring an unprecedented SAA co-catalyst, exhibits exceptionally high photocatalytic hydrogen production activity surpassing its corresponding counterparts.

NATIONAL SCIENCE REVIEW (2021)

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Article Chemistry, Multidisciplinary

Piezo-Photocatalysis over Metal-Organic Frameworks: Promoting Photocatalytic Activity by Piezoelectric Effect

Chenxi Zhang et al.

Summary: The study uses isostructural MOFs for piezo-photocatalysis, finding that UiO-66-NH2(Hf) exhibits significantly higher catalytic activity compared to UiO-66-NH2(Zr) under simultaneous light and ultrasonic irradiation, which is mainly attributed to the piezoelectric effect.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Metal-Organic Framework Decorated Cuprous Oxide Nanowires for Long-lived Charges Applied in Selective Photocatalytic CO2 Reduction to CH4

Hao Wu et al.

Summary: Encapsulating Cu2O nanowires in metal-organic frameworks (MOFs) enhances activity and stability, facilitates charge separation and CO2 uptake, leading to selective photocatalytic CO2 reduction into CH4. This work demonstrates an effective strategy for CO2 conversion by integrating MOFs with metal oxide photocatalyst.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Metal-organic frameworks embedded in a liposome facilitate overall photocatalytic water splitting

Huihui Hu et al.

Summary: By confining MOFs that can promote each half-reaction within liposomal structures and achieving efficient charge separation, overall photocatalytic water splitting has been successfully achieved. The assembly demonstrates ultrafast electron transport and efficient charge separation, resulting in a quantum yield of (1.5 +/- 1)%.

NATURE CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

In Situ Porphyrin Substitution in a Zr(IV)-MOF for Stability Enhancement and Photocatalytic CO2 Reduction

Xiang-Jing Kong et al.

Summary: In this study, a strategy for enhancing stability and functionality in labile Zr(IV)-MOFs through in situ porphyrin substitution has been proposed. The introduction of a robust linear porphyrin ligand significantly improved the chemical stability of the resulting MOFs. The modified MOFs exhibited high catalytic activity in CO2 photoreduction, showing promise for converting unstable MOFs into robust functional materials.

SMALL (2021)

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Article Multidisciplinary Sciences

Phase-enabled metal-organic framework homojunction for highly selective CO2 photoreduction

Yannan Liu et al.

Summary: This study successfully prepared a hierarchical homojunction based on metal-organic frameworks as photocatalysts for CO2 reduction using a convenient synthesis route.

NATURE COMMUNICATIONS (2021)

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Article Multidisciplinary Sciences

Facile electron delivery from graphene template to ultrathin metal-organic layers for boosting CO2 photoreduction

Jia-Wei Wang et al.

Summary: The study demonstrates the construction of metal-organic layers with ordered structure and molecular tunability using graphene oxide as both template and electron mediator, leading to excellent CO2 photoreduction performance.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Multidisciplinary

Interfacial Microenvironment Modulation Boosting Electron Transfer between Metal Nanoparticles and MOFs for Enhanced Photocatalysis

Mingliang Xu et al.

Summary: The presence of surfactants on the surface of metal cocatalysts can significantly affect the electron transfer rate between the metal and MOF, and removing these surfactants can improve the efficiency of photocatalytic hydrogen production.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Inorganic & Nuclear

Band gap engineering of metal-organic frameworks for solar fuel productions

Xiangyang Guo et al.

Summary: Metal-organic frameworks (MOFs) offer a powerful and promising approach for developing novel materials for solar fuel productions by combining the benefits of both inorganic and organic photocatalysts. Understanding the intrinsic correlation between the structures and band gaps of MOFs can guide the construction of visible-light responsive MOFs for solar fuel productions. Various strategies for tuning the band gaps of MOFs are discussed, with a focus on the latest research on photocatalytic H2O and CO2 reduction reactions.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Chemistry, Multidisciplinary

H-Bond-Mediated Selectivity Control of Formate versus CO during CO2 Photoreduction with Two Cooperative Cu/X Sites

Tian-Ci Zhuo et al.

Summary: By integrating photosensitizers and monometallic catalysts into a metal-organic framework, this study achieved highly selective photoreduction of CO2 to formate and revealed the role of hydrogen bonding in the catalytic process.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Metal-Organic Framework Membranes Encapsulating Gold Nanoparticles for Direct Plasmonic Photocatalytic Nitrogen Fixation

Li-Wei Chen et al.

Summary: By using metal-organic framework membranes and gold nanoparticles, direct plasmonic photocatalytic nitrogen fixation to produce ammonia can be achieved, resulting in a higher ammonia evolution rate and lower activation energy under strong irradiation.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Review Chemistry, Multidisciplinary

Chemically Stable Metal-Organic Frameworks: Rational Construction and Application Expansion

Tao He et al.

Summary: Metal-organic frameworks (MOFs) have shown great potential in various fields due to their structural diversity and functional tunability, but their poor chemical stability has hindered their practical applications. Researchers are actively developing efficient strategies to enhance the stability of MOFs and explore new applications under harsh conditions. By designing and synthesizing chemically stable MOFs, significant progress has been made in addressing global challenges related to environment, energy, and food safety.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

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Article Chemistry, Multidisciplinary

Recent Progress in Metal-Organic Frameworks@Cellulose Hybrids and Their Applications

Xiongli Liu et al.

Summary: MOF@cellulose hybrids have shown significant advantages in various applications, addressing the fragility and poor processibility issues of MOFs.

CHINESE JOURNAL OF CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Fe2Mn(μ3-O)(COO)6 Cluster Based Stable MOF for Oxidative Coupling of Amines via Heterometallic Synergy

Ying-Xia Wang et al.

Summary: In this study, a manganese-based heterometallic cluster was introduced as a catalyst to successfully prepare a MOF material capable of effectively catalyzing homo- or cross-coupling of amines at room temperature. The material exhibited high stability and recyclability, providing a new approach for organic synthesis.

CHINESE JOURNAL OF CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Synthesis, Structures of 2D Coordination Layers Metal-Organic Frameworks with Highly Selective CO2 Uptake

Jingjing Jiang et al.

CHINESE JOURNAL OF CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

A Practice of Reticular Chemistry: Construction of a Robust Mesoporous Palladium Metal-Organic Framework via Metal Metathesis

Tao He et al.

Summary: By utilizing deuterated solvent-assisted metal metathesis, a stable azolate Pd-MOF named BUT-33(Pd) was successfully synthesized, showing excellent chemical stability and good performance as a Pd(II) catalyst in various applications such as Suzuki/Heck coupling reactions and photocatalytic CO2 reduction to CH4. This work demonstrates a feasible approach for constructing noble metal based MOFs with high chemical stability and versatile functions through metal metathesis.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Modulating Coordination Environment of Single-Atom Catalysts and Their Proximity to Photosensitive Units for Boosting MOF Photocatalysis

Xing Ma et al.

Summary: A general and facile strategy for the construction of high-loading single-atom catalysts with a tunable coordination microenvironment has been developed based on metal-organic frameworks. The well-accessible and atomically dispersed metal sites possess close proximity to photosensitive units, greatly accelerating charge transfer and promoting photocatalysis. The optimized Ni-1-S/MOF with a unique Ni(I) microenvironment presents excellent photocatalytic H-2 production activity, surpassing other counterparts.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Physical

Self-adaptive dual-metal-site pairs in metal-organic frameworks for selective CO2 photoreduction to CH4

Jian Li et al.

Summary: The study demonstrates a bioinspired photocatalyst with flexible dual-metal-site pairs that enhance CH4 selectivity and production rate. By stabilizing various C1 intermediates, it achieves a highly selective CO2-to-CH4 process.

NATURE CATALYSIS (2021)

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Article Chemistry, Physical

Constructing a photo-enzymatic cascade reaction and its in situ monitoring: enzymes hierarchically trapped in titania meso-porous MOFs as a new photosynthesis platform

Junli Guo et al.

Summary: The study presents a photocatalyst-enzyme coupled approach involving in situ synthesis of a hierarchically porous metal-organic framework in the nanochannels of a TiO2 membrane, leading to trapping of active cytochrome C. The developed system demonstrates visible light activity and allows in situ triggering and monitoring of enzymatic reactions, providing insights into photocatalytically coupled enzyme reactions.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Multidisciplinary

Supramolecular strategies in artificial photosynthesis

Tom Keijer et al.

Summary: Artificial photosynthesis aims to convert solar power into chemical fuel for sustainable energy production, with three fundamental steps including light harvesting, charge-separation, and redox catalysis. Supramolecular chemistry, with its ability to control molecular components precisely through self-assembly processes, can provide important tools for preparing, integrating, and optimizing artificial photosynthetic devices.

CHEMICAL SCIENCE (2021)

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Review Chemistry, Physical

Advanced photocatalysts based on metal nanoparticle/metal-organic framework composites

Jun Guo et al.

Summary: MNP/MOF composite photocatalysts exhibit excellent performance and great potential applications, especially in photocatalytic hydrogen production, carbon dioxide reduction, organic transformation reactions, and photodegradation of pollutants. The challenges and prospects in the current research are also proposed and discussed for further advancement in this hot research field.

NANO RESEARCH (2021)

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Article Chemistry, Multidisciplinary

Stable Heterometallic Cluster-Based Organic Framework Catalysts for Artificial Photosynthesis

Long-Zhang Dong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Chemistry, Inorganic & Nuclear

Application of QD-MOF composites for photocatalysis: Energy production and environmental remediation

Ting Wu et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Article Chemistry, Multidisciplinary

Integration of Enzymes and Photosensitizers in a Hierarchical Mesoporous Metal-Organic Framework for Light-Driven CO2 Reduction

Yijing Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

Photoactivation of Cu Centers in Metal-Organic Frameworks for Selective CO2 Conversion to Ethanol

Lingzhen Zeng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

Metal-Organic Frameworks Significantly Enhance Photocatalytic Hydrogen Evolution and CO2 Reduction with Earth-Abundant Copper Photosensitizers

Xuanyu Feng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

MOFs Conferred with Transient Metal Centers for Enhanced Photocatalytic Activity

Xiaolang Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Chemistry, Inorganic & Nuclear

Metal sulfide/MOF-based composites as visible-light-driven photocatalysts for enhanced hydrogen production from Water splitting

Yang Liu et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Article Chemistry, Multidisciplinary

A Mixed-Metal Porphyrinic Framework Promoting Gas-Phase CO2Photoreduction without Organic Sacrificial Agents

Wen-Yang Gao et al.

CHEMSUSCHEM (2020)

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Article Chemistry, Physical

Toward visible-light-assisted photocatalytic nitrogen fixation: A titanium metal organic framework with functionalized ligands

Hao Huang et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Chemistry, Multidisciplinary

Boosting Interfacial Charge-Transfer Kinetics for Efficient Overall CO2 Photoreduction via Rational Design of Coordination Spheres on Metal-Organic Frameworks

Zhi-Bin Fang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Multidisciplinary Sciences

Filling metal-organic framework mesopores with TiO2for CO2photoreduction

Zhuo Jiang et al.

NATURE (2020)

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Article Chemistry, Physical

Construction of planar-type defect-engineered metal-organic frameworks with both mixed-valence sites and copper-ion vacancies for photocatalysis

Yuan Guo et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Review Thermodynamics

Metal-organic framework as a photocatalyst: Progress in modulation strategies and environmental/energy applications

Sherif A. Younis et al.

PROGRESS IN ENERGY AND COMBUSTION SCIENCE (2020)

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Article Chemistry, Multidisciplinary

Formation of a mixed-valence Cu(i)/Cu(ii) metal-organic framework with the full light spectrum and high selectivity of CO2 photoreduction into CH4

Yajun Gao et al.

CHEMICAL SCIENCE (2020)

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Review Chemistry, Inorganic & Nuclear

Design and applications of water-stable metal-organic frameworks: status and challenges

Xin Zhang et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Review Chemistry, Inorganic & Nuclear

Recent advances in MOF-based photocatalysis: environmental remediation under visible light

Qi Wang et al.

INORGANIC CHEMISTRY FRONTIERS (2020)

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Article Chemistry, Multidisciplinary

Stabilization of Formate Dehydrogenase in a Metal-Organic Framework for Bioelectrocatalytic Reduction of CO2

Yijing Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Physical

Noble metal (Pt, Au@Pd) nanoparticles supported on metal organic framework (MOF-74) nanoshuttles as high-selectivity CO2 conversion catalysts

Yuqing Han et al.

JOURNAL OF CATALYSIS (2019)

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Article Chemistry, Physical

2D Metal Organic Framework Nanosheet: A Universal Platform Promoting Highly Efficient Visible-Light-Induced Hydrogen Production

Jingrun Ran et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Chemistry, Multidisciplinary

Encapsulating Perovskite Quantum Dots in Iron-Based Metal-Organic Frameworks (MOFs) for Efficient Photocatalytic CO2 Reduction

Li-Yuan Wu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Physical

Design and syntheses of MOF/COF hybrid materials via postsynthetic covalent modification: An efficient strategy to boost the visible-light-driven photocatalytic performance

Fei Li et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

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Article Multidisciplinary Sciences

Encapsulating a Ni(II) molecular catalyst in photoactive metal-organic framework for highly efficient photoreduction of CO2

Zhi-Hao Yan et al.

SCIENCE BULLETIN (2019)

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Review Chemistry, Inorganic & Nuclear

Metal or metal-containing nanoparticle@MOF nanocomposites as a promising type of photocatalyst

Yang Liu et al.

COORDINATION CHEMISTRY REVIEWS (2019)

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Article Chemistry, Physical

Size Engineering of Metal-Organic Framework MIL-101(Cr)-Ag Hybrids for Photocatalytic CO2 Reduction

Fan Guo et al.

ACS CATALYSIS (2019)

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Review Chemistry, Multidisciplinary

Artificial Photosynthesis at Efficiencies Greatly Exceeding That of Natural Photosynthesis

Dilek K. Dogutan et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

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Article Chemistry, Multidisciplinary

Switching on the Photocatalysis of Metal-Organic Frameworks by Engineering Structural Defects

Xing Ma et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Review Chemistry, Multidisciplinary

Metal-Organic Frameworks for Photocatalysis and Photothermal Catalysis

Juan-Ding Xiao et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

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Article Chemistry, Multidisciplinary

Adenine Components in Biomimetic Metal-Organic Frameworks for Efficient CO2 Photoconversion

Ning Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Physical

Nanorattle Au@PtAg encapsulated in ZIF-8 for enhancing CO2 photoreduction to CO

Yuqun Su et al.

NANO RESEARCH (2019)

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Article Chemistry, Physical

Monometallic Catalytic Models Hosted in Stable Metal-Organic Frameworks for Tunable CO2 Photoreduction

Xiao-Kun Wang et al.

ACS CATALYSIS (2019)

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Article Chemistry, Multidisciplinary

Facet-dependent photocatalytic hydrogen production of metal-organic framework NH2-MIL-125(Ti)

Fan Guo et al.

CHEMICAL SCIENCE (2019)

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Article Chemistry, Physical

Band gap modulation in zirconium-based metal-organic frameworks by defect engineering

Marco Taddei et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Review Chemistry, Multidisciplinary

Artificial photosynthesis: opportunities and challenges of molecular catalysts

Biaobiao Zhang et al.

CHEMICAL SOCIETY REVIEWS (2019)

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Review Chemistry, Physical

g-C3N4-Based Heterostructured Photocatalysts

Junwei Fu et al.

ADVANCED ENERGY MATERIALS (2018)

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Article Chemistry, Multidisciplinary

Integrating the g-C3N4 Nanosheet with B-H Bonding Decorated Metal-Organic Framework for CO2 Activation and Photoreduction

Guilan Xu et al.

ACS NANO (2018)

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Review Chemistry, Multidisciplinary

Metal-Organic-Framework-Based Catalysts for Photoreduction of CO2

Rui Li et al.

ADVANCED MATERIALS (2018)

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Article Chemistry, Multidisciplinary

Rational Design of MOF/COF Hybrid Materials for Photocatalytic H2 Evolution in the Presence of Sacrificial Electron Donors

Feng-Ming Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Article Chemistry, Multidisciplinary

Zirconium-Porphyrin-Based Metal-Organic Framework Hollow Nanotubes for Immobilization of Noble-Metal Single Atoms

Ting He et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Article Chemistry, Physical

Microwave irradiation induced UIO-66-NH2 anchored on graphene with high activity for photocatalytic reduction of CO2

Xiaojun Wang et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Article Chemistry, Physical

Construction of heterostructured ZnIn2S4@NH2-MIL-125(Ti) nanocomposites for visible-light-driven H-2 production

Hong Liu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Article Chemistry, Multidisciplinary

Charge-Transfer within Zr-Based Metal-Organic Framework: The Role of Polar Node

Andrea Van Wyk et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Review Chemistry, Physical

Metal-Organic Framework Based Catalysts for Hydrogen Evolution

Bingjun Zhu et al.

ADVANCED ENERGY MATERIALS (2018)

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Article Chemistry, Physical

MOF-based ternary nanocomposites for better CO2 photoreduction: roles of heterojunctions and coordinatively unsaturated metal sites

Xiang He et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Article Chemistry, Physical

Photocatalytic hydrogen generation from a visible-light responsive metal-organic framework system: the impact of nickel phosphide nanoparticles

Stavroula Kampouri et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Article Chemistry, Multidisciplinary

Hierarchically Engineered Mesoporous Metal-Organic Frameworks toward Cell-free Immobilized Enzyme Systems

Peng Li et al.

CHEM (2018)

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Review Chemistry, Multidisciplinary

Metal-Organic Frameworks Encapsulating Active Nanoparticles as Emerging Composites for Catalysis: Recent Progress and Perspectives

Guodong Li et al.

ADVANCED MATERIALS (2018)

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Article Chemistry, Multidisciplinary

Photosensitizing Metal-Organic Layers for Efficient Sunlight-Driven Carbon Dioxide Reduction

Guangxu Lan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Review Nanoscience & Nanotechnology

Interfacing nature's catalytic machinery with synthetic materials for semi-artificial photosynthesis

Nikolay Kornienko et al.

NATURE NANOTECHNOLOGY (2018)

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Article Nanoscience & Nanotechnology

Bacteria photosensitized by intracellular gold nanoclusters for solar fuel production

Hao Zhang et al.

NATURE NANOTECHNOLOGY (2018)

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Article Chemistry, Multidisciplinary

Highly effective photoreduction of CO2 to CO promoted by integration of CdS with molecular redox catalysts through metal-organic frameworks

Chunjun Chen et al.

CHEMICAL SCIENCE (2018)

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Article Chemistry, Multidisciplinary

Ti-Substituted Keggin-Type Polyoxotungstate as Proton and Electron Reservoir Encaged into Metal-Organic Framework for Carbon Dioxide Photoreduction

Shu-Mei Liu et al.

ADVANCED MATERIALS INTERFACES (2018)

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Article Energy & Fuels

Bias-free photoelectrochemical water splitting with photosystem II on a dye-sensitized photoanode wired to hydrogenase

Katarzyna P. Sokol et al.

NATURE ENERGY (2018)

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Review Chemistry, Multidisciplinary

Semiconducting quantum dots for artificial photosynthesis

Xu-Bing Li et al.

NATURE REVIEWS CHEMISTRY (2018)

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Article Chemistry, Physical

Unveiling Charge-Separation Dynamics in CdS/Metal-Organic Framework Composites for Enhanced Photocatalysis

Hai-Qun Xu et al.

ACS CATALYSIS (2018)

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Article Chemistry, Physical

Core@Shell CsPbBr3@Zeolitic Imidazolate Framework Nanocomposite for Efficient Photocatalytic CO2 Reduction

Zi-Cheng Kong et al.

ACS ENERGY LETTERS (2018)

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Article Chemistry, Multidisciplinary

Acid and Base Resistant Zirconium Polyphenolate-Metalloporphyrin Scaffolds for Efficient CO2 Photoreduction

Er-Xia Chen et al.

ADVANCED MATERIALS (2018)

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Integration of Plasmonic Effects and Schottky Junctions into Metal-Organic Framework Composites: Steering Charge Flow for Enhanced Visible-Light Photocatalysis

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