Journal
CHEMISTRY LETTERS
Volume 51, Issue 10, Pages 1015-1017Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.220334
Keywords
Ag(I) complex; Photoluminescence; Crystal structure
Categories
Funding
- JSPS KAKENHI [17K05816]
- Seikei University
Ask authors/readers for more resources
We synthesized a new type of asymmetric binuclear Ag(I) complex, which showed relatively strong green luminescence in the solid state.
We synthesized a new type of asymmetric binuclear Ag(I) complex, [Ag-2(dppaO(2))(2)(dppbz)] (1), consisting of two chelating dppaO(2)(-) ligands (dppaO(2)(-) = N,N-bis(diphenylphosphino)-amide-dioxide) and one bridging dppbz ligand (dppbz = 1,2-bis(diphenylphosphino)-benzene). According to X-ray crystal structure analysis, the two Ag(I) ions were adjacent to each other and were bridged by both the dppbz ligands and one of the oxygen atoms in the dppaO(2)(-) ligands. Complex 1 showed relatively strong green luminescence in the solid state.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available