Self-assembly of MXene-decorated stearic acid/ionic liquid phase change material emulsion for effective photo-thermal conversion and storage

As a typical latent functionally thermal fluid with large energy storage capacity and good liquidity, phase change material emulsion (PCME) plays a broad and important role in solar energy utilization. However, the hightemperature instability and supercooling problems of PCME limit its practical application. The ionic liquid (IL)-based PCME allows for the possibility of being used as a heat transfer fluid (HTF) under more extreme temperature conditions. In this work, stearic acid (SA)/IL PCME, prepared by one-step self-assembly of MXene nanosheets at the SA/IL interface, can effectively absorb and convert solar energy into thermal energy. Furthermore, MXene-decorated SA/IL PCMEs have good high-temperature stability, little supercooling degree (0.9-3.1 degrees C), and large energy storage capacity. The maximum apparent specific heat capacity and average absorbance of the MXene-decorated SA/IL PCME are 4.5 and 303.1 times higher than those of IL, respectively. Under 2 sun irradiation, the 0.05-20 wt% MXene-decorated SA/IL PCME achieves high photo-thermal conversion efficiencies (91.3% at 68.9 degrees C, 39.4% at 115.1 degrees C) due to its large energy storage capacity and excellent optical absorption property. The simple interfacial self-assembly provides a promising strategy to prepare

Automated summary

In this study, high-temperature stable, low supercooling, and high energy storage capacity phase change material emulsion (PCME) based on stearic acid (SA) and ionic liquid (IL) was prepared by the self-assembly of MXene nanosheets at the SA/IL interface. The PCME can effectively absorb and convert solar energy into thermal energy, and has excellent optical absorption properties and high photo-thermal conversion efficiencies.