4.7 Article

Lightweight porous silica-alumina ceramics with ultra-low thermal conductivity

Journal

CERAMICS INTERNATIONAL
Volume 49, Issue 4, Pages 6479-6486

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2022.10.165

Keywords

Composites; Porosity; Thermal conductivity; Strength

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Silica-alumina composite porous ceramics with high porosity and low thermal conductivity were prepared by the particle-stabilized foaming method. They have the potential to serve as thermal insulation material in the spacecraft industry.
Thermal protection has always been an important issue in the energy, environment and aerospace fields. Porous ceramics produced by the particle-stabilized foaming method have become a competitive material for thermal protection because of their low density and low thermal conductivity. However, the study of porous ceramics for composite systems using particle-stabilized foaming method was relatively rare. Here, silica-alumina composite porous ceramics were prepared by particle-stabilized foaming method, which was achieved by tailoring the surface charges of silica and alumina through adjustment of the pH. Porous ceramics exhibited porosity as high as 97.49% and thermal conductivity (25 degrees C) as low as 0.063 W m(-1) K-1. The compressive strength of porous ceramics sintered at 1500 degrees C with a solid content of 30 wt% could reach 0.765 MPa. Based on the light weight and excellent thermal insulation properties, the composite porous ceramic could be used as a potential thermal insulation material in the spacecraft industry.

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