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A review on mechanism, applications and influencing factors of carbon quantum dots based photocatalysis

Journal

CERAMICS INTERNATIONAL
Volume 48, Issue 24, Pages 35986-35999

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2022.10.116

Keywords

CQDs; Photocatalysis; Mechanism; Applications; Influencing factors

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This review introduces the applications of CQDs in photocatalysis, including their role in enhancing the reaction rate, absorbing more visible light, and inhibiting electron-hole recombination. It also summarizes the factors affecting photocatalytic activity to guide the adjustment of reaction conditions.
CQDs (carbon quantum dots) have attracted a lot of attention in the field of photocatalysis due to its absorption of visible light, up-conversion luminescence, rich free groups on the surface and low cost. CQDs doped semi-conductor can improve the photocatalytic reaction rate by the following three points: (1) adjust the band structure of photocatalyst; (2) facilitate the absorption of more visible light; (3) facilitate electron transfer and inhibits electron-hole recombination. In this review, the mechanism (photosensitizer, electron acceptor, up -conversion luminescence, etc.) and applications (photocatalytic degradation of organic pollutants, reduction of heavy metals, etc.) of CQDs in the field of photocatalysis are briefly introduced. Finally, the factors affecting the photocatalytic activity were summarized in order to adjust the reaction conditions and show high catalytic activity. It is hoped that this review can provide insights and inspiration for the development of CQDs in the field of photocatalysis.

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