4.7 Article

A novel BaMg1.98Zn0.02V2O8 ceramic with low dielectric loss and good temperature stability for low temperature co-fired ceramic technology

Journal

CERAMICS INTERNATIONAL
Volume 48, Issue 24, Pages 36186-36192

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2022.08.175

Keywords

BaMg 2-x Zn x V 2 O 8 ceramic; Low dielectric loss; Good temperature stability; LTCC

Funding

  1. Major Projects of Science and Tech- nology in Tianjin
  2. [18ZXJMTG00020]

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In this study, a series of BaMg2-xZnxV2O8 ceramics were successfully synthesized by ionic substitution. The relationship between surface morphology and microwave properties was analyzed, and it was found that the substitution of Mg2+ with Zn2+ can improve densification, lower sintering temperature, and reduce dielectric loss significantly. The BaMg1.98Zn0.02V2O8 ceramic exhibited excellent microwave dielectric properties at the optimum sintering temperature, making it suitable for low-temperature co-firing technology.
In this paper, a series of BaMg2-xZnxV2O8 (0.02 <= x <= 0.08) ceramic has been obtained by ionic substitution at the Mg-site of BaMg2V2O8 ceramics through the conventional solid-state reaction method. The relationship between the surface morphology and the microwave properties of ceramic samples was analyzed intensively. The results showed that the substitution of Mg2+ by an appropriate amount of Zn2+ can promote their densification, lower their sintering temperature, and reduce the dielectric loss of BaMg2V2O8 ceramics significantly. The BaMg1.98Zn0.02V2O8 ceramic exhibits microwave dielectric properties as er ---13.4, Q x f --- 178,760 GHz, of ---14.9 ppm/degrees C at the optimum sintering temperature (940 degrees C). This indicates that the ceramic prepared in this work, which combines low dielectric loss, good temperature stability, and low-temperature sintering ability, can be an ideal microwave dielectric material for low-temperature co-firing technology.

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